Write the structure of the alkene formed by dehydrohalogenation of 1-bromo-1-methylcyclohexane with alcoholic KOH
Experts are working on it..
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
If NaCl is doped with 10-3mol % of SrCl2, what is the concentration of cation vacancies?
Explain the following terms:
(i) Electrophoresis
(ii) Coagulation
(iii) Dialysis
(iv) Tyndall effect.
What happens when white phosphorus is heated with concentrated NaO Hsolution in an inert atmosphere of CO2?
Why does the conductivity of a solution decrease with dilution?
Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution.
The following results have been obtained during the kinetic studies of the reaction: 2A + B → C + D
Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate of formation of D/mol L - 1 min - 1 |
I | 0.1 | 0.1 |
6.0 × 10 - 3 |
II | 0.3 | 0.2 |
7.2 × 10 - 2 |
III | 0.3 | 0.4 |
2.88 × 10 - 1 |
IV | 0.4 | 0.1 |
2.40 × 10 - 2 |
Determine the rate law and the rate constant for the reaction.
Write main differences between the properties of white phosphorus and red phosphorus.
For the reaction:
2A + B → A2B
the rate = k[A][B]2with k= 2.0 x 10-6mol-2L2s-1. Calculate the initial rate of the reaction when [A] = 0.1 mol L-1, [B] = 0.2 mol L-1. Calculate the rate of reaction after [A] is reduced to 0.06 mol L-1.
19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.0°C. Calculate the van't Hoff factor and dissociation constant of fluoroacetic acid.
What is meant by positive & negative deviations from raoult’s law & how is the sign of ΔmixH related to positive & negative deviations from Raoult’s law?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?