If 0.561 g of KOH is dissolved in water to give 200 mL of solution at 298 K. Calculate the concentrations of potassium, hydrogen and hydroxyl ions. What is its pH?
[KOH(aq)] = 0.561 / (1/5)g/L
= 2.805 g/L
= 2.805 x 1/56.11 M
= 0.05M
KOH(aq) → K+(aq) + OH-(aq)
[OH-] = 0.05M = [K+]
[H-] [H+] = Kw
[H+] Kw / [OH-]
= 10-14 / 0.05 = 2x10-13 M
∴ pH = 12.70
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
If the speed of light is 3.0 × 108 ms–1, calculate the distance covered by light in 2.00 ns.
What is Kc for the following equilibrium when the equilibrium concentration of each substance is: [SO2]= 0.60 M, [O2] = 0.82 M and [SO3] = 1.90 M ?
2SO2(g) + O2(g) ↔ 2SO3(g)
A certain particle carries 2.5 × 10–16C of static electric charge. Calculate the number of electrons present in it.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Consider the following species:
N3–, O2–, F–, Na+, Mg2+ and Al3+
(a) What is common in them?
(b) Arrange them in the order of increasing ionic radii.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
Describe the usefulness of water in biosphere and biological systems.
How do you expect the metallic hydrides to be useful for hydrogen storage? Explain.
Describe the method, which can be used to separate two compounds with different solubilities in a solvent S.
Find energy of each of the photons which
(i) correspond to light of frequency 3× 1015 Hz.
(ii) have wavelength of 0.50 Å.