Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Yes.All contain the same number of the respective molecules.
No. The root mean square speed of neon is the largest.
Since the three vessels have the same capacity, they have the same volume.
Hence, each gas has the same pressure, volume, and temperature.
According to Avogadro's law, the three vessels will contain an equal number of the respective molecules. This number is equal to Avogadro's number, N= 6.023 × 1023.
The root mean square speed (vrms) of a gas of mass m, and temperature T, is given by the relation:
vrms = underroot 3kT / m
Where, k is Boltzmann constant
For the given gases, k and T are constants.
Hence vrmsdepends only on the mass of the atoms, i.e.,
vrms ∝ underroot 1/m
Therefore, the root mean square speed of the molecules in the three cases is not the same. Among neon, chlorine, and uranium hexafluoride, the mass of neon is the smallest. Hence, neon has the largest root mean square speed among the given gases.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Rain is falling vertically with a speed of 30 m s–1. A woman rides a bicycle with a speed of 10 m s–1 in the north to south direction. What is the direction in which she should hold her umbrella?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
An electric heater supplies heat to a system at a rate of 100W. If system performs work at a rate of 75 Joules per second. At what rate is the internal energy increasing?
A travelling harmonic wave on a string is described by
y(x,t) = 7.5sin [0.0050x + 12t + π/4]
(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?
(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
Precise measurements of physical quantities are a need of science. For example, to ascertain the speed of an aircraft, one must have an accurate method to find its positions at closely separated instants of time. This was the actual motivation behind the discovery of radar in World War II. Think of different examples in modern science where precise measurements of length, time, mass etc. are needed. Also, wherever you can, give a quantitative idea of the precision needed.
An aircraft executes a horizontal loop at a speed of 720 km/h with its wings banked at 15°. What is the radius of the loop?
Use the formula v = √ γP/ρ to explain why the speed of sound in air (a) is independent of pressure, (b) increases with temperature, (c) increases with humidity.
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
It is a well known fact that during a total solar eclipse the disk of the moon almost completely covers the disk of the Sun. From this fact and from the information you can gather from examples 2.3 and 2.4, determine the approximate diameter of the moon.
Estimate the average mass density of a sodium atom assuming its size to be about 2.5 Å. (Use the known values of Avogadro’s number and the atomic mass of sodium). Compare it with the density of sodium in its crystalline phase : 970 kg m–3. Are the two densities of the same order of magnitude ? If so, why ?
A man walks on a straight road from his home to a market 2.5 km away with a speed of 5 km h –1. Finding the market closed, he instantly turns and walks back home with a speed of 7.5 km h–1. What is the
a) magnitude of average velocity, and
b) average speed of the man over the interval of time (i) 0 to 30 min, (ii) 0 to 50 min, (iii) 0 to 40 min?
[Note: You will appreciate from this exercise why it is better to define average speed as total path length divided by time, and not as magnitude of average velocity. You would not like to tell the tired man on his return home that his average speed was zero!]