One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10-10 m
Volume of hydrogen atom = 4/3 π r3
= 4/3 x 22/7 x (0.5 x 10-10)3
= 0.524 x 1030 m3
1 mole of hydrogen contains 6.023 × 1023 hydrogen atoms.
∴ Volume of 1 mole of hydrogen atoms = 6.023 × 1023 × 0.524 × 10-30
= 3.16 × 10-7 m3
Molar volume of 1 mole of hydrogen atoms at STP,
Vm = 22.4 L = 22.4 × 10-3 m3
∴ Vm / Va = 22.4 x 10-3 / 3.16 × 10-7 = 7.08 × 104
Hence, the molar volume is 7.08 × 104 times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Rain is falling vertically with a speed of 30 m s–1. A woman rides a bicycle with a speed of 10 m s–1 in the north to south direction. What is the direction in which she should hold her umbrella?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
Use the formula v = √ γP/ρ to explain why the speed of sound in air (a) is independent of pressure, (b) increases with temperature, (c) increases with humidity.
Read each statement below carefully and state, with reasons, if it is true or false:
(a) The net acceleration of a particle in circular motion is always along the radius of the circle towards the centre
(b) The velocity vector of a particle at a point is always along the tangent to the path of the particle at that point
(c) The acceleration vector of a particle in uniform circular motion averaged over one cycle is a null vector
The blades of a windmill sweep out a circle of area A. (a) If the wind flows at a velocity v perpendicular to the circle, what is the mass of the air passing through it in time t?(b) What is the kinetic energy of the air? (c) Assume that the windmill converts 25% of the wind's energy into electrical energy, and that A = 30 m2, v = 36 km/h and the density of air is 1.2 kg m-3. What is the electrical power produced?
The position-time (x-t) graphs for two children A and B returning from their school O to their homes P and Q respectively are shown in Fig. 3.19. Choose the correct entries in the brackets below;
(a) (A/B) lives closer to the school than (B/A)
(b) (A/B) starts from the school earlier than (B/A)
(c) (A/B) walks faster than (B/A)
(d) A and B reach home at the (same/different) time
(e) (A/B) overtakes (B/A) on the road (once/twice).
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
A narrow sound pulse (for example, a short pip by a whistle) is sent across a medium.
(a) Does the pulse have a definite (i) frequency, (ii) wavelength, (iii) speed of propagation?
(b) If the pulse rate is 1 after every 20 s, (that is the whistle is blown for a split of second after every 20 s), is the frequency of the note produced by the whistle equal to or 0.05 Hz?
Two trains A and B of length 400 m each are moving on two parallel tracks with a uniform speed of 72 km h–1 in the same direction, with A ahead of B. The driver of B decides to overtake A and accelerates by 1 m/s2. If after 50 s, the guard of B just brushes past the driver of A, what was the original distance between them?
Textbooks on science may give you a wrong impression that studying science is dry and all too serious and that scientists are absent-minded introverts who never laugh or grin. This image of science and scientists is patently false. Scientists, like any other group of humans, have their share of humorists, and many have led their lives with a great sense of fun and adventure, even as they seriously pursued their scientific work. Two great physicists of this genre are Gamow and Feynman. You will enjoy reading their books listed in the Bibliography.
( i ) The time period of a body having simple harmonic motion depends on the mass m of the body and the force constant k:
T =2π √m/k
A simple pendulum exhibits simple harmonic motion. Then why does the time period of a pendulum not depend upon its mass?
( ii ) For small angle oscillations, a simple pendulum exhibits simple harmonic motion ( more or less). For larger angles of oscillation, detailed analysis show that T is greater than 2π√ l/g. Explain.
( iii ) A boy with a wristwatch on his hand jumps from a helicopter. Will the wrist watch give the correct time during free fall?
( iv ) Find the frequency of oscillation of a simple pendulum that is free falling from a tall bridge.
A car moving along a straight highway with a speed of 126 km h–1 is brought to a stop within a distance of 200 m. What is the retardation of the car (assumed uniform), and how long does it take for the car to stop?