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Enumerate the reactions of D-glucose which cannot be explained by its ...

Enumerate the reactions of D-glucose whi | Class 12 Chemistry Chapter Biomolecules, Biomolecules NCERT Solutions

Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter Biomolecules. This page offers a step-by-step solution to the specific question from Exercise 2, Question 10: . With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.

Question 10:

Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.

Answer:

(1) Aldehydes give 2, 4-DNP test, Schiff's test, and react with NaHSO₄ to form the hydrogen sulphite addition product. However, glucose does not undergo these reactions.

(2) The pentaacetate of glucose does not react with hydroxylamine. This indicates that a free -CHO group is absent from glucose.

(3) Glucose exists in two crystalline forms - ∝ and β. The ∝-form (m.p. = 419 K) crystallises from a concentrated solution of glucose at 303 K and the β-form (m.p = 423 K) crystallises from a hot and saturated aqueous solution at 371 K. This behaviour cannot be explained by the open chain structure of glucose.

Other Questions of Chapter Biomolecules

What are nucleic acids? Mention their two important functions.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

What is the difference between a nucleoside and a nucleotide?

How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?

Classify the following into monosaccharides and disaccharides.

Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose

What are enzymes?

What are the expected products of hydrolysis of lactose?

The two strands in DNA are not identical but are complementary. Explain.

What are the common types of secondary structure of proteins?

What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO₃

Popular questions of class 12 Chemistry

How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

Give simple chemical tests to distinguish between the following pairs of compounds.

(i) Propanal and Propanone

(ii) Acetophenone and Benzophenone

(iii) Phenol and Benzoic acid

(iv) Benzoic acid and Ethyl benzoate

(v) Pentan-2-one and Pentan-3-one

(vi) Benzaldehyde and Acetophenone

(vii) Ethanal and Propanal

A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.

A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL^-1, then what shall be the molarity of the solution?

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂pressure at 298 K.

Calculate the mass of a non-volatile solute (molar mass 40 g mol^-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.

Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.

How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na₂CO₃ and NaHCO₃ containing equimolar amounts of both?

If NaCl is doped with 10^-3mol % of SrCl₂, what is the concentration of cation vacancies?

Recently Viewed Questions of Class 12 Chemistry

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂pressure at 298 K.

What are the different oxidation states exhibited by the lanthanoids?

The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:

Experiment	A/ mol L^{- 1}	B/ mol L^{- 1}	Initial rate/mol L^{- 1} min^{- 1}
I	0.1	0.1	2.0 × 10^{- 2}
II	--	0.2	4.0 × 10^{- 2}
III	0.4	0.4	--
IV	--	0.2	2.0 × 10^{- 2}

Mention the conditions required to maximise the yield of ammonia.

Ionic solids conduct electricity in molten state but not in solid state. Explain.

Describe the oxidising action of potassium dichromate and write the ionicequations for its reaction with:

(i) iodide

(ii) iron

(II) solution and

(iii) H₂S

What type of solids are electrical conductors, malleable and ductile?

Write the structure of the major organic product in each of the following reactions:

Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.

How will you bring about the following conversions?

(i) Ethanol to but-1-yne

(ii) Ethane to bromoethene

(iii) Propene to 1-nitropropane

(iv) Toluene to benzyl alcohol

(v) Propene to propyne

(vi) Ethanol to ethyl fluoride

(vii) Bromomethane to propanone

(viii) But-1-ene to but-2-ene

(ix) 1-Chlorobutane to n-octane

(x) Benzene to biphenyl.

Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

Read the question carefully and focus on the core concept being asked.
Reference examples and data from the chapter when answering questions about Biomolecules.
Review previous year question papers to get an idea of how such questions may be framed in exams.
Practice answering questions within the time limit to improve your speed and accuracy.
Discuss your answers with your teachers or peers to get feedback and improve your understanding.

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Comments

Ayush
Jul 19, 2019

What how to learn such a big answer.

Ayush
Jul 19, 2019

What

Komal
Mar 10, 2019

Thank you

Ankit ara
Dec 26, 2016

Better

manasa
Jun 20, 2016

really useful