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This chapter belongs to a previous NCERT/CBSE curriculum and is not part of the current 2026-27 chapter list. Removed in 2022-23.
Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter The p-Block Elements. This page offers a step-by-step solution to the specific question from Exercise 1, Question 8:
What happens when white phosphorus is heated with concentrated NaO Hsolution in an inert atmosphere of CO2?
. With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.What happens when white phosphorus is heated with concentrated NaO Hsolution in an inert atmosphere of CO2?
Phosphorus exist in many allotropic forms. The three main forms are:
1) White Phosphorus
2) Red Phosphorus
3) Black Phosphorus
White Phosphorus is obtained from phosphorite rock with coke and sand. It consist of P4 units.The four P- atoms lie at the corners of a regular tetrahedron. It is less stable and therefore more reactive than other allotropic forms of Phosphorus. On heating with concentrated NaOH in an inert environment of CO2 following reaction takes place:

Phosphine (PH3) is formed.This reaction is an example of disproportionation reaction in which oxidation state of phosphorus decreases from 0 in P4 to -3 in PH3,while it increases from 0 in P4 to +1 in NaH2PO2.
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
| Experiment |
A/ mol L - 1 |
B/ mol L - 1 |
Initial rate/mol L - 1 min - 1 |
| I | 0.1 | 0.1 |
2.0 × 10 - 2 |
| II | -- | 0.2 |
4.0 × 10 - 2 |
| III | 0.4 | 0.4 | -- |
| IV | -- | 0.2 |
2.0 × 10 - 2 |
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Welcome to the NCERT Solutions for Class 12 Chemistry - Chapter . This page offers a step-by-step solution to the specific question from Excercise 1 , Question 8: What happens when white phosphorus is heated with concentrated NaO Hsolution in an inert atmosphere ....
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Thank u so much
Thanks
Thank you sir
That's not table that is stable
Nice...too much explanation
Topper
Thank u very much
Exlent sir
Good
Not bad but not satisfied too