Calculate the energy required for the process
The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1
For H like particles,
En = - 2π2mZ2e4 / n2h2
For H atom I.E = E – E1 = 0 – (- 2π2me4 / 12h2) = 2π2me4 / h2
= 2.18x 10-18J /atom (given)
For the given process, energy required = En – E1
= 0 - ( - 2π2me4 / 12h2)
= 4 x 2π2me4 / h2
= 4 x 2.18 x 10-18J
= 8.72 x 10-18 J
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
How does the atomic hydrogen or oxy-hydrogen torch function for cutting and welding purposes? Explain.
Explain the important aspects of resonance with reference to the ion.
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
If the diameter of a carbon atom is 0.15 nm, calculate the number of carbon atoms which can be placed side by side in a straight line across length of scale of length 20 cm long.
Starting with sodium chloride how would you proceed to prepare
(i) sodium metal (ii) sodium hydroxide (iii) sodium peroxide (iv) sodium carbonate?
How do you account for the formation of ethane during chlorination of methane?
What do you understand by bond pairs and lone pairs of electrons? Illustrate by giving one example of each type.
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
An alkene 'A' on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and IUPAC name of 'A'.
Electromagnetic radiation of wavelength 242 nm is just sufficient to ionise the sodium atom. Calculate the ionisation energy of sodium in kJ mol–1.