Comment on each of the following observa | Class 11 Chemistry Chapter The s Block Elements, The s Block Elements NCERT Solutions

Welcome to the NCERT Solutions for Class 11 Chemistry - Chapter The s Block Elements. This page offers a step-by-step solution to the specific question from Exercise 1, Question 26: . With detailed answers and explanations for each chapter, students can strengthen their understanding and prepare confidently for exams. Ideal for CBSE and other board students, this resource will simplify your study experience.

Question 26:

Comment on each of the following observations:

(a) The mobilities of the alkali metal ions in aqueous solution are Li⁺ < Na⁺ < K⁺ < Rb⁺ < Cs⁺

(b) Lithium is the only alkali metal to form a nitride directly.

Answer:

(a) On moving down the alkali group, the ionic and atomic sizes of the metals increase. The given alkali metal ions can be arranged in the increasing order of their ionic sizes as:

Li⁺ < Na⁺ < K⁺ < Rb⁺ < Cs⁺

Smaller the size of an ion, the more highly is it hydrated. Since Li⁺ is the smallest, it gets heavily hydrated in an aqueous solution. On the other hand, Cs⁺ is the largest and so it is the least hydrated. The given alkali metal ions can be arranged in the decreasing order of their hydrations as:

Li⁺ > Na⁺ > K⁺ > Rb⁺ > Cs⁺

Greater the mass of a hydrated ion, the lower is its ionic mobility. Therefore, hydrated Li⁺ is the least mobile and hydrated Cs⁺ is the most mobile. Thus, the given alkali metal ions can be arranged in the increasing order of their mobilities as:

Li⁺< Na⁺ < K⁺ < Rb⁺ < Cs⁺

(b) Unlike the other elements of group 1, Li reacts directly with nitrogen to form lithium nitride. This is because Li⁺ is very small in size and so its size is the most compatible with the N^3- ion. Hence, the lattice energy released is very high. This energy also overcomes the high amount of energy required for the formation of the N^3- ion.

(i) Ionisation enthalpy

(ii) Enthalpy of hydration

(iii) Enthalpy of vaporisation

The combined effect of these factors is approximately the same for Ca, Sr, and Ba. Hence, their electrode potentials are nearly constant.

Other Questions of Chapter The s Block Elements

Describe the importance of the following: (i) limestone (ii) cement (iii) plaster of paris.

Explain the significance of sodium, potassium, magnesium and calcium inbiological fluids.

In what ways lithium shows similarities to magnesium in its chemical behaviour?

Draw the structure of (i) BeCl₂ (vapour) (ii) BeCl₂ (solid).

Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?

What happens when

(i) sodium metal is dropped in water ?

(ii) sodium metal is heated in free supply of air ?

(iii) sodium peroxide dissolves in water ?

Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?

What happens when

(i) magnesium is burnt in air

(ii) quick lime is heated with silica

(iii) chlorine reacts with slaked lime

(iv) calcium nitrate is heated ?

Discuss the general characteristics and gradation in properties of alkaline earth metals.

When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

Popular questions of class 11 Chemistry

Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.

(ii) 1 mole of carbon is burnt in 16 g of dioxygen.

(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

The mass of an electron is 9.1 × 10^–31 kg. If its K.E. is 3.0 × 10^–25 J, calculate its wavelength.

Calculate the wavelength of an electron moving with a velocity of 2.05 × 10⁷ ms^–1.

Balance the following redox reactions by ion – electron method :

(a) MnO₄^–(aq) + I^–(aq) → MnO_{2 (s)} + I_2(s) (in basic medium)

(b) MnO₄ ^– (aq) + SO_{2 (g)}→ Mn²⁺ (aq) + HSO₄^– (aq) (in acidic solution)

(d) Cr₂O₇ ^2– + SO_2(g) → Cr³⁺ _(aq) + SO₄^2–(aq) (in acidic solution)

In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Which one of the following will have largest number of atoms?

(i) 1 g Au (s)

(ii) 1 g Na (s)

(iii) 1 g Li (s)

(iv) 1 g of Cl2(g)

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

Recently Viewed Questions of Class 11 Chemistry

How would you convert the following compounds into benzene?

(i) Ethyne (ii) Ethene (iii) Hexane

Explain structures of diborane and boric acid.

For the following equilibrium, K_c= 6.3 × 10¹⁴ at 1000 K

NO (g) + O₃ (g) ↔ NO₂ (g) + O₂(g)

Both the forward and reverse reactions in the equilibrium are elementary bimolecular reactions. What is K_c, for the reverse reaction?

Describe the change in hybridisation (if any) of the Al atom in the following reaction.

Find out the value of K_c for each of the following equilibria from the value of K_p:

(i) 2NOCl (g) ↔ 2NO (g) + Cl₂ (g); Kp = 1.8 × 10^–2 at 500 K

(ii) CaCO₃ (s) ↔ CaO(s) + CO₂(g); Kp = 167 at 1073 K

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

Find energy of each of the photons which

(i) correspond to light of frequency 3× 1015 Hz.

(ii) have wavelength of 0.50 Å.

Calculate the number of kJ of heat necessary to raise the temperature of 60.0 g of aluminium from 35°C to 55°C. Molar heat capacity of Al is 24 J mol^–1 K^–1.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Write Lewis symbols for the following atoms and ions:

S and S2–; Al and Al3+; H and H–

Study Tips for Answering NCERT Questions:

NCERT questions are designed to test your understanding of the concepts and theories discussed in the chapter. Here are some tips to help you answer NCERT questions effectively:

Read the question carefully and focus on the core concept being asked.
Reference examples and data from the chapter when answering questions about The s Block Elements.
Review previous year question papers to get an idea of how such questions may be framed in exams.
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