What are the harmful effects of photochemical smog and how can they be controlled?
EFFECTS OF PHOTOCHEMICAL SMOG:
Photochemical smog: Owing to the presence of NO2 and O3, causing corrosion of metals, stones, rubber, and painted surfaces, it becomes oxidizing. The other major components of photochemical smog are PAN, acrolein, and formaldehyde. Both PAN and ozone are eye irritants, while nitric oxide (formed from NO2) causes nose and throat irritation. At higher concentrations, photochemical smog leads to chest pain, headaches, throat dryness, and various respiratory ailments.
CONTROL MEASURES:
Photochemical smog is obtained from the burning of fossil fuels and automobile fuels that emit NO2 and hydrocarbons, which in turn form ozone, PAN, and other chemicals. To prevent the release of NO2 and hydrocarbons into the atmosphere, the use of catalytic converters in automobiles is recommended. Plantation of plants such as Pinus, Juniparur, Quercus, Pyrus, and Vitis is also advised as they have the capability to metabolize NO2.
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
Write down the reactions involved during the formation of photochemical smog.
Explain tropospheric pollution in 100 words.
What are the reactions involved for ozone layer depletion in the stratosphere?
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
Statues and monuments in India are affected by acid rain. How?
What do you mean by green chemistry? How will it help decrease environmental pollution?
What is smog? How is classical smog different from photochemical smog?
What do you mean by ozone hole? What are its consequences?
A large number of fish are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish kill.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids?
(a) Cl3CCOOH > Cl2CHCOOH > ClCH2COOH
(b) CH3CH2COOH > (CH3)2CHCOOH > (CH3)3C.COOH
Why is Li2CO3 decomposed at a lower temperature whereas Na2CO3 at higher temperature?
What are electron deficient compounds? Are BCl3 and SiCl4 electron deficient species? Explain.
Electromagnetic radiation of wavelength 242 nm is just sufficient to ionise the sodium atom. Calculate the ionisation energy of sodium in kJ mol–1.
The hydroxides and carbonates of sodium and potassium are easily soluble in water while the corresponding salts of magnesium and calcium are sparingly soluble in water. Explain.
Write chemical equations for combustion reaction of the following hydrocarbons:
(i) Butane
(ii) Pentene
(iii) Hexyne
(iv) Toluene
Which of the two: OO2NCH2CH2O- or CH3CH2O- is expected to be more stable and why?
Which of the following pairs of elements would have a more negative electron gain enthalpy?
(i) O or F
(ii) F or Cl
Give the number of electrons in the species , H2 and
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