Write the names of isotopes of hydrogen. What is the mass ratio of these isotopes?
Hydrogen has three isotopes.
They are:
1. Protium, 1H1,
2. Deuterium, 2H1 or D, and
3. Tritium, 3H1 or T
The mass ratio of protium, deuterium and tritium is 1:2:3.
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the structures of H2O and H2O2.
Write chemical reactions to show the amphoteric nature of water.
Arrange the following
(i) CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
(ii) LiH, NaH and CsH in order of increasing ionic character.
(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.
(iv) NaH, MgH2 and H2O in order of increasing reducing property.
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
What is meant by 'demineralised' water and how can it be obtained?
What causes the temporary and permanent hardness of water?
How does H2O2 behave as a bleaching agent?
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Write bond line formulas for : Isopropyl alcohol, 2,3-Dimethyl butanal, Heptan-4- one.
What is the total number of sigma and pi bonds in the following molecules?
(a) C2H2 (b) C2H4
The value of Kc for the reaction
3O2 (g) ↔ 2O3 (g) is 2.0 ×10–50 at 25°C.
If the equilibrium concentration of O2 in air at 25°C is 1.6 ×10–2, what is the concentration of O3?
Which of the following carbocation is most stable ?
Calculate the standard enthalpy of formation of CH3OH(l) from the following data:
CH3OH (l) + 3/2 O2(g) → CO2(g) + 2H2O(l) ; ΔrH0 = –726 kJ mol–1
C(g) + O2(g) → CO2(g) ; ΔcH0 = –393 kJ mol–1
H2(g) + 1/2 O2(g) → H2O(l) ; ΔfH0 = –286 kJ mol–1.
Predict which of the following reaction will have appreciable concentration of reactants and products:
a) Cl2 (g) ↔ 2Cl (g) Kc = 5 ×10–39
b) Cl2 (g) + 2NO (g) ↔ 2NOCl (g) Kc = 3.7 × 108
c) Cl2 (g) + 2NO2 (g) ↔ 2NO2Cl (g) Kc = 1.8
Draw the resonance structures for the following compounds. Show the electron shift using curved-arrow notation.
(a) C6H5OH
(b) C6H5NO2
(c) CH3CH=CHCHO
(d) C6H5–CHO
(e) C6 H5 - C+H2
(f) CH3CH = CHC+H2
Determine the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are 69.9 and 30.1 respectively. Given that the molar mass of the oxide is 159.69 g mol–1.
Write the resonance structures for SO3, NO2 and .
Following results are observed when sodium metal is irradiated with different wavelengths.
Calculate (a) threshold wavelength and, (b) Planck’s constant.
λ (nm) | 500 | 450 |
400 |
v × 10–5 (cm s–1) | 2.55 | 4.35 | 5.35 |