Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?
Dihydrogen is prepared by the electrolysis of acidified or alkaline water using platinum electrodes. Generally, 15 - 20% of an acid (H2SO4) or a base (NaOH) is used.
Reduction of water occurs at the cathode as:
2H2O + 2e- → 2H2 + 2OH-
At the anode, oxidation of OH-ions takes place as:
2OH- → H2O + ½ O2 + 2e-
∴ Net reaction can be represented as:
H2O(I) → H2(g) + ½ O2(g)
Electrical conductivity of pure water is very low owing to the absence of ions in it. Therefore, electrolysis of pure water also takes place at a low rate. If an electrolyte such as an acid or a base is added to the process, the rate of electrolysis increases. The addition of the electrolyte makes the ions available in the process for the conduction of electricity and for electrolysis to take place.
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the structures of H2O and H2O2.
Write chemical reactions to show the amphoteric nature of water.
Arrange the following
(i) CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
(ii) LiH, NaH and CsH in order of increasing ionic character.
(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.
(iv) NaH, MgH2 and H2O in order of increasing reducing property.
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
What is meant by 'demineralised' water and how can it be obtained?
What causes the temporary and permanent hardness of water?
How does H2O2 behave as a bleaching agent?
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
What do you mean by Biochemical Oxygen Demand (BOD)?
A mixture of dihydrogen and dioxygen at one bar pressure contains 20% by weight of dihydrogen. Calculate the partial pressure of dihydrogen.
Write Lewis dot symbols for atoms of the following elements: Mg, Na, B, O, N, Br.
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.
Which one of the following alkali metals gives hydrated salts?
(a) Li (b) Na (c) K (d) Cs
Ionic product of water at 310 K is 2.7 x 10-14. What is the pH of neutral water at this temperature?
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
At 473 K, equilibrium constant Kc for decomposition of phosphorus pentachloride, PCl5 is 8.3 ×10-3. If decomposition is depicted as,
PCl5 (g) ↔ PCl3 (g) + Cl2 (g) ΔrH0 = 124.0 kJ mol–1
(a) write an expression for Kc for the reaction.
(b) what is the value of Kc for the reverse reaction at the same temperature ?
(c) what would be the effect on Kc if (i) more PCl5 is added (ii) pressure is increased (iii) the temperature is increased ?
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