How can saline hydrides remove traces of water from organic compounds?
Saline hydrides areionic in nature. They react with water to form a metal hydroxide along with the liberation of hydrogen gas. The reaction of saline hydrides with water can be represented as:
AH(s) + H2O(l) → AOH(aq) + H2(g)
(where, A = Na, Ca,……)
When added to an organic solvent, they react with water present in it. Hydrogen escapes into the atmosphere leaving behind the metallic hydroxide. The dry organic solvent distills over.
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the structures of H2O and H2O2.
Write chemical reactions to show the amphoteric nature of water.
Arrange the following
(i) CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
(ii) LiH, NaH and CsH in order of increasing ionic character.
(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.
(iv) NaH, MgH2 and H2O in order of increasing reducing property.
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
What is meant by 'demineralised' water and how can it be obtained?
What causes the temporary and permanent hardness of water?
How does H2O2 behave as a bleaching agent?
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
The value of Kc for the reaction
3O2 (g) ↔ 2O3 (g) is 2.0 ×10–50 at 25°C.
If the equilibrium concentration of O2 in air at 25°C is 1.6 ×10–2, what is the concentration of O3?
Describe the importance of the following: (i) limestone (ii) cement (iii) plaster of paris.
In the alkane H3C – CH2 – C(CH3)2 – CH2 – CH(CH3)2, identify 1°,2°,3° carbon atoms and give the number of H atoms bonded to each one of these.
A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate
(i) empirical formula,
(ii) molar mass of the gas, and
(iii) molecular formula.
Among the following pairs of orbitals which orbital will experience the larger effective nuclear charge?
(i) 2s and 3s,
(ii) 4d and 4f,
(iii) 3d and 3p
What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
(a)
(b)
(c)
Consider the reactions :
2 S2O2– 3 (aq) + I2(s) → S4 O2– 6(aq) + 2I – (aq)
S2O2– 3(aq) + 2Br2(l) + 5 H2O(l) → 2SO2–4(aq) + 4Br–(aq) + 10H+(aq)
Why does the same reductant, thiosulphate react differently with iodine and bromine ?
Differentiate between the principle of estimation of nitrogen in an organic compound by
(i) Dumas method and
(ii) Kjeldahl's method.
How can you explain higher stability of BCl3 as compared to TlCl3?
In terms of period and group where would you locate the element with Z =114?