How much energy is required to ionise a H atom if the electron occupies n = 5 orbit? Compare your answer with the ionization enthalpy of H atom (energy required to remove the electron from n =1 orbit).
The expression of energy is given by,
Where,
Z = atomic number of the atom
n = principal quantum number
For ionization from n1 = 5 to ,
Therefore ΔE = E2- E1 = - 21.8 X10-19 (1/n22-1/n12)
= 21.8 X10-19(1/n22-1/n12)
= 21.8 X10-19 (1/52-1/∞)
= 8.72 x 10-20 J
For ionization from 1st orbit, n1= 1,
Therefore ΔE’ = 21.8x10-19(1/12-1/∞)
= 21.8x10-19 J
Now ΔE’/ ΔE = 21.8x10-19 / 8.72x10-20 = 25
Thus the energy required to remove electron from 1st orbit is 25 times than the required to electron from 5th orbit.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Convert the following into basic units:
(i) 28.7 pm
(ii) 15.15 pm
(iii) 25365 mg
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Describe the importance of the following: (i) limestone (ii) cement (iii) plaster of paris.
Whenever a reaction between an oxidising agent and a reducing agent is carried out, a compound of lower oxidation state is formed if the reducing agent is in excess and a compound of higher oxidation state is formed if the oxidising agent is in excess. Justify this statement giving three illustrations.
If the speed of light is 3.0 × 108 ms–1, calculate the distance covered by light in 2.00 ns.
Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) E° for M2+(aq) (where M = Ca, Sr or Ba) is nearly constant.
Explain the formation of H2 molecule on the basis of valence bond theory.
Which hybrid orbitals are used by carbon atoms in the following molecules?
(a)CH3–CH3;
(b) CH3–CH=CH2;
(c) CH3-CH2-OH;
(d) CH3-CHO
(e) CH3COOH
Describe the theory associated with the radius of an atom as it
(a) gains an electron
(b) loses an electron
Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural formula of the alkene?
Mast wala answer dene ke liye thanks sir
What the hell
Thanks
Such a worst answer I have ever seen
How at first n2=infinity
Grammatical mistake
Thanks ,any how good
Typing must be clear
I think some steps are missing
Thank u sir