Class 11 Chemistry - Chapter The p Block Elements NCERT Solutions | Consider the compounds, BCl3 and CCl4. H

What happens when

(a) Borax is heated strongly,

(b) Boric acid is added to water,

(c) Aluminium is treated with dilute NaOH,

(d) BF₃ is reacted with ammonia?

Give reasons:

(i) Conc. HNO₃ can be transported in aluminium container.

(ii) A mixture of dilute NaOH and aluminium pieces is used to open drain.

(iii) Graphite is used as lubricant.

(iv) Diamond is used as an abrasive.

(v) Aluminium alloys are used to make aircraft body.

(vi) Aluminium utensils should not be kept in water overnight.

(vii) Aluminium wire is used to make transmission cables.

Write reactions to justify amphoteric nature of aluminium.

Why does boron trifluoride behave as a Lewis acid?

Discuss the pattern of variation in the oxidation states of
(i) B to Tl and (ii) C to Pb.

Write balanced equations for:

(i) BF₃ + LiH →

(ii) B₂H₆ + H₂O →

(iii) NaH + B₂H₆ →

(iv) H₃BO₃ 

(v) Al + NaOH →

(vi) B₂H₆ + NH₃ →

How can you explain higher stability of BCl₃ as compared to TlCl₃?

A certain salt X, gives the following results.

(i) Its aqueous solution is alkaline to litmus.

(ii) It swells up to a glassy material Yon strong heating.

(iii) When conc. H₂SO₄ is added to a hot solution of X, white crystal of an acid Z separates out.

Write equations for all the above reactions and identify X, Y and Z.

(a) Classify following oxides as neutral, acidic, basic or amphoteric:

CO, B₂O₃, SiO₂, CO2, Al₂O₃, PbO₂, Tl₂O₃

(b) Write suitable chemical equations to show their nature.

Rationalise the given statements and give chemical reactions :

(i) Lead(II) chloride reacts with Cl₂ to give PbCl₄.

(ii) Lead(IV) chloride is highly unstable towards heat.

(iii) Lead is known not to form an iodide, PbI₄.

How do you account for the formation of ethane during chlorination of methane?

What are hybridisation states of each carbon atom in the following compounds ?

(i) CH₂=C=O,

(ii) CH₃CH=CH₂,

(iii) (CH₃)₂CO,

(iv) CH₂=CHCN,

(v) C₆H₆

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

What are the common physical and chemical features of alkali metals?

Calculate the molecular mass of the following:
(i) H₂O
(ii) CO₂
(iii) CH₄

Assign oxidation number to the underlined elements in each of the following species:

(a) NaH₂PO₄

(b) NaHSO₄

(c) H₄P₂O₇

(d) K₂MnO₄

(e) CaO₂

(f) NaBH₄

(g) H₂S₂O₇

(h) KAl(SO₄)₂.12 H₂O

What is the basic theme of organisation in the periodic table?

Explain the formation of a chemical bond.

Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Enthalpy of combustion of carbon to CO₂ is -393.5 kJ mol^-1. Calculate the heat released upon formation of 35.2 g of CO₂ from carbon and dioxygen gas.

In Milikan’s experiment, static electric charge on the oil drops has been obtained by shining X-rays.

If the static electric charge on the oil drop is –1.282 × 10^–18C, calculate the number of electrons present on it.

In three moles of ethane (C₂H₆), calculate the following:
(i) Number of moles of carbon atoms.
(ii) Number of moles of hydrogen atoms.
(iii) Number of molecules of ethane.

Explain the formation of H₂ molecule on the basis of valence bond theory.

In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.

(i) 300 atoms of A + 200 molecules of B

(ii) 2 mol A + 3 mol B

(iii) 100 atoms of A + 100 molecules of B

(iv) 5 mol A + 2.5 mol B

(v) 2.5 mol A + 5 mol B

Using s, p, d notations, describe the orbital with the following quantum numbers.

(a) n = 1, l = 0;

(b) n = 3; l =1

(c) n = 4; l = 2;

(d) n = 4; l =3.

How would you convert the following compounds into benzene?

(i) Ethyne         (ii) Ethene          (iii) Hexane

Consider the reactions:

(a) H₃PO_2(aq) + 4 AgNO_3(aq) + 2 H₂O_(l) → H₃PO_4(aq) + 4Ag_(s) + 4HNO_3(aq)

(b) H₃PO_2(aq) + 2CuSO_4(aq) + 2 H₂O_(l) → H₃PO_4(aq) + 2Cu_(s) + H₂SO_4(aq)

(c) C₆H₅CHO_(l) + 2 [Ag (NH₃)₂]⁺_(aq) + 3OH^-_(aq) → C₆H₅COO^-_(aq) + 2Ag_(s) + 4NH_3(aq) + 2 H₂O_(l)

(d) C₆H₅CHO_(l) + 2Cu²⁺_(aq) + 5OH^-_(aq) → No change observed.

What inference do you draw about the behaviour of Ag⁺and Cu²⁺from these reactions?

Given the standard electrode potentials,

K⁺/K = -2.93V, Ag⁺/Ag = 0.80V,

Hg²⁺/ Hg = 0.79V

Mg²⁺/ Mg = -2.37V. Cr³⁺/ Cr = -0.74V

Arrange these metals in their increasing order of reducing power.

Justify giving reactions that among halogens, fluorine is the best oxidant and among hydrohalic compounds, hydroiodic acid is the best reductant.