Which hybrid orbitals are used by carbon atoms in the following molecules?
(a)CH3–CH3;
(b) CH3–CH=CH2;
(c) CH3-CH2-OH;
(d) CH3-CHO
(e) CH3COOH
Hybrid orbital are formed by the overlapping of orbitals having almost same energy.
Single bond= one sigma bond = sp3 hybridization
Double bond = one sigma bond + one pie bond = sp2 hybridization
Triple bond = one sigma bond + two pie bond = sp hybridization
(a)
According to structure, C1 & C2 are making 4 sigma bonds(single bond) each with the help of one s hybrid orbital & 3 p hybrid orbital, hence C1& C2 are sp3 hybridised
(b)
Here C1 is making 4 sigma bond therefore it s sp3 hybridised , while C2 and C3 are making a double bond( 1 sigma + 1 pie bond ) therefore they both are sp2 hybridized.
(c)
Both the carbons C1 & C2 are making single bond(sigma bond),therefore they are sp3hybridized.
(d)
From the structure it is clear that C1 is making sigma bonds only, therefore it is sp3 hybridised.C2 is making a double bond therefore it is sp2 hybridised.
C1 is sp3 hybridized and C2 is sp2 hybridized.
(e)
Here C1 is making a sigma bond therefore it is in sp3 hybridization state, while C2 is making a double bond ,it is in sp2 hybridised state.
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Describe the change in hybridisation (if any) of the Al atom in the following reaction.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
How can domestic waste be used as manure?
Chlorine is used to purify drinking water. Excess of chlorine is harmful. The excess of chlorine is removed by treating with sulphur dioxide. Present a balanced equation for this redox change taking place in water.
What is the maximum number of emission lines when the excited electron of an H atom in n = 6 drops to the ground state?
Explain tropospheric pollution in 100 words.
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How can saline hydrides remove traces of water from organic compounds?
Discuss the chemistry of Lassaigne's test.
Critical temperature for carbon dioxide and methane are 31.1 °C and –81.9 °C respectively. Which of these has stronger intermolecular forces and why?
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(a) Na2O2and water
(b) KO2 and water
(c) Na2O and CO2
What happens when
(i) magnesium is burnt in air
(ii) quick lime is heated with silica
(iii) chlorine reacts with slaked lime
(iv) calcium nitrate is heated ?
myself whore sharma like vary nice answer
Well explained
Very well explained
Well explained
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