What do you mean by Biochemical Oxygen Demand (BOD)?
Biochemical oxygen demand is the amount of oxygen required by bacteria to decompose organic matter in a certain volume of sample of water. Clean water would have a BOD value of less than 5 ppm, whereas highly polluted water has a BOD value of more than or equal to 17 ppm.
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
What are the harmful effects of photochemical smog and how can they be controlled?
Write down the reactions involved during the formation of photochemical smog.
Explain tropospheric pollution in 100 words.
What are the reactions involved for ozone layer depletion in the stratosphere?
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
Statues and monuments in India are affected by acid rain. How?
What do you mean by green chemistry? How will it help decrease environmental pollution?
What is smog? How is classical smog different from photochemical smog?
What do you mean by ozone hole? What are its consequences?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
At a certain temperature and total pressure of 105 Pa, iodine vapour contains 40% by volume of I atoms
I2(g) ↔ 2l (g)
Calculate Kp for the equilibrium.
What do you understand by the terms:
(i) hydrogen economy
(ii) hydrogenation
(iii) 'syngas'
(iv) water-gas shift reaction
(v) fuel-cell ?
The best and latest technique for isolation, purification and separation of organic compounds is:
(a) Crystallisation
(b) Distillation
(c) Sublimation
(d) Chromatography
Write chemical reactions to justify that hydrogen peroxide can function as an oxidizing as well as reducing agent.
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
The bromine atom possesses 35 electrons. It contains 6 electrons in 2p orbital, 6 electrons in 3p orbital and 5 electrons in 4p orbital. Which of these electron experiences the lowest effective nuclear charge?
The ionization constant of propanoic acid is 1.32 x 10-5. Calculate the degree of ionization of the acid in its 0.05M solution and also its pH. What will be its degree of ionization if the solution is 0.01M in HCl also?
Arrange the bonds in order of increasing ionic character in the molecules: LiF, K2O, N2, SO2 and ClF3.
Potassium carbonate cannot be prepared by Solvay process. Why?
Ethyl acetate is formed by the reaction between ethanol and acetic acid and the equilibrium is represented as:
CH3COOH (l) + C2H5OH (l) ↔ CH3COOC2H5 (l) + H2O (l)
(i) Write the concentration ratio (reaction quotient), Qc, for this reaction (note: water is not in excess and is not a solvent in this reaction)
(ii) At 293 K, if one starts with 1.00 mol of acetic acid and 0.18 mol of ethanol, there is 0.171 mol of ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant.
(iii) Starting with 0.5 mol of ethanol and 1.0 mol of acetic acid and maintaining it at 293 K, 0.214 mol of ethyl acetate is found after sometime. Has equilibrium been reached?