Electromagnetic radiation of wavelength 242 nm is just sufficient to ionise the sodium atom. Calculate the ionisation energy of sodium in kJ mol–1.
From E= hv or hc/ λ, we have λ = 242nm or 242 x 10-9m
C = 3 x 108 m/s
h = 6.62 x 10-34 Js
Now putting these values in the equation we get
E= (6.62 x 10-34 Js x 3 x 108 m/s) / (242 x 10-9m)
= 0.0821 x 10-17 J/atom
Or
E = (0.0821 x 10-17 ) / (1000 x 6.02 x 1023)
= 494 KJ/mol
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
The pH of 0.1M solution of cyanic acid (HCNO) is 2.34. Calculate the ionization constant of the acid and its degree of ionization in the solution.
What is the minimum volume of water required to dissolve 1g of calcium sulphate at 298 K? (For calcium sulphate, Ksp is 9.1 x 10-6).
The reaction:
CH3CH2I + KOH(aq) → CH3CH2OH + KI
is classified as :
(a) electrophilic substitution
(b) nucleophilic substitution
(c) elimination
(d) addition
Describe the theory associated with the radius of an atom as it
(a) gains an electron
(b) loses an electron
Define electronegativity. How does it differ from electron gain enthalpy?
It has been found that the pH of a 0.01M solution of an organic acid is 4.15. Calculate the concentration of the anion, the ionization constant of the acid and its pKa.
Calculate the oxidation number of sulphur, chromium and nitrogen in H2SO5, Cr2O2- 7 and NO– 3. Suggest structure of these compounds. Count for the fallacy.
At 450K, Kp= 2.0 × 1010/bar for the given reaction at equilibrium.
2SO2(g) + O2(g) ↔ 2SO3 (g)
What is Kc at this temperature ?
Thermodynamically the most stable form of carbon is
(a) diamond (b) graphite (c) fullerenes (d) coal
Elements of group 14
(a) exhibit oxidation state of +4 only
(b) exhibit oxidation state of +2 and +4
(c) form M2-and M4+ion
(d) form M2+and M4+ions
Thq a lot to give this answers
I have problem in dealing with numerical
Thank
Y
What about if use hydrogen instead of sodium
Tq saralstudy
Why cant we use -13.6Z^2
Why cant we use -13.6Z^2
How it's come?
Right solution