Write one difference in each of the following:
(a) Multimolecular colloid and Associated colloid
(b) Coagulation and Peptization
(c) Homogeneous catalysis and Heterogeneous catalysis
OR
(a) Write the dispersed phase and dispersion medium of milk.
(b) Write one similarity between Physisorption and chemisorption.
(c) Wrtie the chemical method by which Fe(OH)3 sol is prepared from FeCl3.
(a) In Multimolecular colloid the atoms or molecules are held by weak vander walls forces and In associated colloid. They behave as normal electrolytes at low concentrations and colloidal only at high concentrations.
(b) The process of Changing the colloid particle in a solution in to insoluble precipitate by addition of suitable electrolyte is known as cogulation and conversion of freshly precipitated substance in to colloidal solution by shaking with the suitable electrolyte is called peptization
(c) In Homogenous catalysis the catalyst and reactant are in the same phase and In Hetrogeneous catalysis the catalyst is in different phase than are the reactants.
OR
(a) Milk is an emulsion in which both the dispersed phase and the dispersion medium are in liquid state. In milk, liquid fat is dispersed in water. So fat is the dispersed phase and water is the dispersion medium.
(b) Both are surface phenomenon.
(c) A colloidal solution of Fe[OH]3 is prepared when concentrated solution of ferric chloride is added drop wise to hot water.
FeCl3 + 3H2O → Fe[OH]3 + 3HCl
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
If NaCl is doped with 10-3mol % of SrCl2, what is the concentration of cation vacancies?
Suggest two materials other than hydrogen that can be used as fuels in fuel cells.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Boiling point of water at 750 mm Hg is 99.63°C. How much sucrose is to be added to 500 g of water such that it boils at 100°C.Molal elevation constant for water is 0.52 K kg mol-1.
Complete the following reactions:
(i) C2H4 + O2 →
(ii) 4Al + 3O2 →
Sea is the greatest source of some halogens. Comment.
Give the IUPAC names of the following compounds:
(i) CH3CH(Cl)CH(Br)CH3
(ii) CHF2CBrClF
(iii) ClCH2C≡CCH2Br
(iv) (CCl3)3CCl
(v) CH3C(p-ClC6H4)2CH(Br)CH3
(vi) (CH3)3CCH=CClC6H4I-p
Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Explain how does the -OH group attached to a carbon of benzene ring activate it towards electrophilic substitution?