Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Ionization enthalpy is the minimum amount of energy which is needed to remove the loosely bound electron from a isolated gaseous atom to form a cation.
It is given that the energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J.
Therefore, the energy required to remove that electron from the ground state of hydrogen atom is 2.18 × 10–18 J.
so Ionization enthalpy of atomic hydrogen = 2.18 × 10–18 J
Hence, ionization enthalpy of atomic hydrogen in terms of J mol–1 = 2.18 × 10–18 × 6.02 × 1023 J mol–1 = 1.31 × 106 J mol–1
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F–
(ii) Ar
(iii) Mg2+
(iv) Rb+
What is the basic difference between the terms electron gain enthalpy and electronegativity?
Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is:
(a) B > C > Si > N > F
b) Si > C > B > N > F
(c) F > N > C > B > Si
d) F > N > C > Si > B
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
How does atomic radius vary in a period and in a group? How do you explain the variation?
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N
(b) F > O > Cl > N
(c) Cl > F > O > N
(d) O > F > N > Cl
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Calculate the entropy change in surroundings when 1.00 mol of H2O(l) is formed under standard conditions. ΔfH0 = –286 kJ mol–1.
Potassium carbonate cannot be prepared by Solvay process. Why?
Explain structures of diborane and boric acid.
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
What is the wavelength of light emitted when the electron in a hydrogen atom undergoes transition from an energy level with n = 4 to an energy level with n = 2?
If the starting material for the manufacture of silicones is RSiCl3, write the structure of the product formed.
Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?
Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
What are the necessary conditions for any system to be aromatic?
What happens when
(i) magnesium is burnt in air
(ii) quick lime is heated with silica
(iii) chlorine reacts with slaked lime
(iv) calcium nitrate is heated ?
Energy of electron has negative value which shows that electron has loosened that energy to come to the hydrogen nucleus hence it is required to give back that same amount of energy to the electron to get out of the hydrogen atom
Very well understood
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