Write chemical reactions to justify that hydrogen peroxide can function as an oxidizing as well as reducing agent.
Hydrogen peroxide, H2O2 acts as an oxidizing as well as a reducing agent in both acidic and alkaline media.
Reactions involving oxidizing actions are:
1) 2Fe2+ + 2H+ + H2O2 → 2Fe3+ + 2H2O
2) Mn2+ + H2O2 → Mn4+ + 2OH-
3) PbS + 4H2O2 → PbSO4 + 4H2O
4) 2Fe2+ + H2O2 → 2 Fe3+ + 2OH-
Reactions involving reduction actions are:
1) 2MnO-4 + 6H+ + 5H2O2 → 2Mn2+ + 8H2O + 5O2
2) I2 + H2O2 + 2OH- → 2l- + 2H2O + O2
3) HOCl + H2O2 → H3O+ + Cl- + O2
4) 2MnO-4 + 3H2O2 → 2MnO2 + 3O2 + 2H2O + 2OH-
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the structures of H2O and H2O2.
Write chemical reactions to show the amphoteric nature of water.
Arrange the following
(i) CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
(ii) LiH, NaH and CsH in order of increasing ionic character.
(iii) H-H, D-D and F-F in order of increasing bond dissociation enthalpy.
(iv) NaH, MgH2 and H2O in order of increasing reducing property.
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer.
What is meant by 'demineralised' water and how can it be obtained?
What causes the temporary and permanent hardness of water?
How does H2O2 behave as a bleaching agent?
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the following reactions:
(a) 2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)
(b) HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH-(aq) → 2Ag(s) + HCOO-(aq) + 4NH3(aq) + 2H2O(l)
(c) HCHO (l) + 2Cu2+(aq) + 5 OH-(aq) → Cu2O(s) + HCOO-(aq) + 3H2O(l)
(d) N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)
(e) Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)
The concentration of hydrogen ion in a sample of soft drink is 3.8 × 10–3 M. what is its pH?
The equilibrium constant expression for a gas reaction is,
Write the balanced chemical equation corresponding to this expression.
Explain why pure liquids and solids can be ignored while writing the equilibrium constant expression?
Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
Explain the principle of paper chromatography.
Write the resonance structures for SO3, NO2 and .
The reaction:
CH3CH2I + KOH(aq) → CH3CH2OH + KI
is classified as :
(a) electrophilic substitution
(b) nucleophilic substitution
(c) elimination
(d) addition
Calculate the entropy change in surroundings when 1.00 mol of H2O(l) is formed under standard conditions. ΔfH0 = –286 kJ mol–1.