Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Isoelectronic species = they are the species belonging to different atoms or ions which have same number of electrons but different magnitude of nuclear charge.
Now, A positive charge denotes the loss of an electron & A negative charge denotes the gain of an electron by a species.
1) Number of electrons in sodium (Na) = 11
Therefore, Number of electrons in (Na+) = 10
2) Number of electrons in K+ = 18
3) Number of electrons in Mg2+ = 10
4) Number of electrons in Ca2+ = 18
5) Number of electrons in sulphur (S) = 16
∴ Number of electrons in S2- = 18
6) Number of electrons in argon (Ar) = 18
Hence, the following are isoelectronic species:
1) Na+ and Mg2+ (10 electrons each)
2) K+, Ca2+, S2– and Ar (18 electrons each)
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
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(ii) the kinetic energy of the emission, and
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Find energy of each of the photons which
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(i) CH2=C=O,
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(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
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Calculate the molecular mass of the following:
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(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
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(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
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Find the equilibrium pressure of all gases if 10.0 bar of HBr is introduced into a sealed container at 1024K.
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