The ejection of the photoelectron from the silver metal in the photoelectric effect experiment can be stopped by applying the voltage of 0.35 V when the radiation 256.7 nm is used. Calculate the work function for silver metal.
From the principle of conservation of energy, the energy of an incident photon (E) is equal to the sum of the work function (W0) of radiation and its kinetic energy (K.E) i.e.,
Energy of incident radiation(E)= hc/λ = (6.626x10-34)(3x108)/(256.7x 10-9)
= 7.74x10-19 J
Since the potential applied gives the kinetic energy to the radiation ,therefore K.E of the electron = 0.35Ev
Therefore work function = 4.83 – 0.35 = 4.48 eV
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Discuss the pattern of variation in the oxidation states of
(i) B to Tl and (ii) C to Pb.
How can saline hydrides remove traces of water from organic compounds?
Statues and monuments in India are affected by acid rain. How?
Write the names of isotopes of hydrogen. What is the mass ratio of these isotopes?
How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
If the density of methanol is 0.793 kg L–1, what is its volume needed for making 2.5 L of its 0.25 M solution?
What effect does branching of an alkane chain has on its boiling point?
Discuss the principle of estimation of halogens, sulphur and phosphorus present in an organic compound.
The type of hybridisation of boron in diborane is
(a) sp (b) sp2 (c) sp3 (d) dsp2
Explain the important aspects of resonance with reference to the ion.
Conver 7.74 * 10^-19 J in eV to get 4.83.
4.83 kaha se aya
See description on ncert solution
Please explain properlyð
Volt cannot be converted into Joule without the value of Coulomb.
Therefore work function = 4.83 â 0.35 = 4.48 eV how did 4.83 come?