Question 15

A man went door to door posing as a goldsmith. He promised to bring back the glitter of old and dull gold ornaments. An unsuspecting lady gave a set of gold bangles to him which he dipped in a particular solution. The bangles sparkled like new but their weight was reduced drastically. The lady was upset but after a futile argument the man beat a hasty retreat. Can you play the detective to find out the nature of the solution he had used?

Answer

The gold metal is dipped in the solution of aqua regia i.e. 3:1 mixture of conc. HCl and conc. HNO3. Aqua regia is a fuming, highly corrosive liquid. It dissolves gold in it. When the gold ornaments are dipped into aqua regia, the outer layer of gold gets dissolved and the inner shiny layer appears. That is why the weight of gold ornaments drastically decreases.

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