What will be the mass of one 12C atom in g?
1 mole of carbon= 6.022x 1023 carbon atoms = 12 g carbon
Or 6.022x 1023 atoms of carbon = 12 g of carbon
Therefore 1 atoms of carbon = 12/6.022x 1023 x 1= 1.993 x 10-23 g of carbon
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous hydrochloric acid according to the reaction
4HCl(aq) + MnO2(s) → 2H2O(l) + MnCl2(aq) + Cl2(g)
How many grams of HCl react with 5.0 g of manganese dioxide?
Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% dioxygen by mass.
A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction,
CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?
Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol–1
A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate
(i) empirical formula,
(ii) molar mass of the gas, and
(iii) molecular formula.
How many significant figures are present in the following?
(i) 0.0025
(ii) 208
(iii) 5005
(iv) 126,000
(v) 500.0
(vi) 2.0034
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Define hydrogen bond. Is it weaker or stronger than the van der Waals forces?
What are pesticides and herbicides? Explain giving examples.
If the velocity of the electron in Bohr’s first orbit is 2.19 × 106 ms–1, calculate the de Broglie wavelength associated with it.
If B-Cl bond has a dipole moment, explain why BCl3 molecule has zero dipole moment.
For the reaction at 298 K,
2A + B → C
ΔH = 400 kJ mol-1and ΔS = 0.2 kJ K-1mol-1
At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?
Calculate the pH of the following solutions:
(a) 2 g of TlOH dissolved in water to give 2 litre of solution.
(b) 0.3 g of Ca(OH)2 dissolved in water to give 500 mL of solution.
(c) 0.3 g of NaOH dissolved in water to give 200 mL of solution.
(d) 1mL of 13.6 M HCl is diluted with water to give 1 litre of solution.
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Complete the following chemical reactions.
(i) PbS(s) + H2O2(aq) →
(ii) MnO-4(aq) + H2O2(aq) →
(iii) CaO(s) + H2O(g) →
(iv) AlCl3(g) + H2O(I) →
(v) Ca3N2(s) + H2O(I) →
Classify the above into (a) hydrolysis, (b) redox and (c) hydration reactions.
What is meant by 'demineralised' water and how can it be obtained?
How does H2O2 behave as a bleaching agent?
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