What is the lowest value of n that allows g orbitals to exist?
Quantum numbers = the set of four number which gives a complete information about the electrons in an atom.
Here n = principal quantum number
As for any value ‘n’ of principal quantum number, the Azimuthal quantum number (l) can have a value from zero to (n – 1).
For n = 1 (K shell) has l = 0 (one subshell)
For n = 2 (L shell) has l= 0,1 (2 subshell)
For n = 3 (M shell) has l = 0,1,2 (3 subshell)
For n = 4 (N shell) has l = 0,1,2,3 (4 subshell)
For n = 5 (O shell) has l = 0,1,2,3,4 (5subshell)
∴ For l = 4, minimum value of n = 5
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
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Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
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(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
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(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
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(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Convert the following into basic units:
(i) 28.7 pm
(ii) 15.15 pm
(iii) 25365 mg
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How much time would it take to distribute one Avogadro number of wheat grains, if 1010 grains are distributed each second?
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Which of the following carbocation is most stable ?
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List gases which are responsible for greenhouse effect.
Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per following endothermic reaction:
CH4 (g) + H2O (g) ↔ CO (g) + 3H2 (g)
(a) Write as expression for Kp for the above reaction.
(b) How will the values of Kp and composition of equilibrium mixture be affected by
(i) increasing the pressure
(ii) increasing the temperature
(iii) using a catalyst ?
What is meant by 'demineralised' water and how can it be obtained?
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