Class 11 Chemistry - Chapter States of Matter NCERT Solutions | What will be the minimum pressure requir

At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?

Density of a gas is found to be 5.46 g/dm³ at 27 °C at 2 bar pressure. What will be its density at STP?

Calculate the temperature of 4.0 mol of a gas occupying 5 dm³ at 3.32 bar.

(R = 0.083 bar dm³ K^–1 mol^–1).

A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?

Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm³ at 27°C. R = 0.083 bar dm³ K^–1 mol^–1.

Calculate the volume occupied by 8.8 g of CO₂ at 31.1°C and 1 bar pressure.

R = 0.083 bar L K^–1 mol^–1.

34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?

2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?

What would be the SI unit for the quantity pV²T ²/n?

Pay load is defined as the difference between the mass of displaced air and the mass of the balloon. Calculate the pay load when a balloon of radius 10 m, mass 100 kg is filled with helium at 1.66 bar at 27°C. (Density of air = 1.2 kg m^–3 and R = 0.083 bar dm³ K^–1 mol^–1).

How do you account for the formation of ethane during chlorination of methane?

What are hybridisation states of each carbon atom in the following compounds ?

(i) CH₂=C=O,

(ii) CH₃CH=CH₂,

(iii) (CH₃)₂CO,

(iv) CH₂=CHCN,

(v) C₆H₆

What are the common physical and chemical features of alkali metals?

Calculate the molecular mass of the following:
(i) H₂O
(ii) CO₂
(iii) CH₄

Assign oxidation number to the underlined elements in each of the following species:

(a) NaH₂PO₄

(b) NaHSO₄

(c) H₄P₂O₇

(d) K₂MnO₄

(e) CaO₂

(f) NaBH₄

(g) H₂S₂O₇

(h) KAl(SO₄)₂.12 H₂O

What is the basic theme of organisation in the periodic table?

Explain the formation of a chemical bond.

Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.

Dual behaviour of matter proposed by de Broglie led to the discovery of electron microscope often used for the highly magnified images of biological molecules and other type of material. If the velocity of the electron in this microscope is 1.6 × 10⁶ ms^–1, calculate de Broglie wavelength associated with this electron.

Calcium carbonate reacts with aqueous HCl to give CaCl₂ and CO₂ according to the reaction,

CaCO_3(s) + 2 HCl_(aq) → CaCl_2(aq) + CO_2(g) + H₂O_(l)

What mass of CaCO₃ is required to react completely with 25 mL of 0.75 M HCl?

(a) Classify following oxides as neutral, acidic, basic or amphoteric:

CO, B₂O₃, SiO₂, CO2, Al₂O₃, PbO₂, Tl₂O₃

(b) Write suitable chemical equations to show their nature.

A sample of pure PCl5 was introduced into an evacuated vessel at 473 K. After equilibrium was attained, concentration of PCl5 was found to be 0.5 × 10^–1 mol L^–1. If value of Kc is 8.3 × 10^–3, what are the concentrations of PCl₃ and Cl₂ at equilibrium?

PCl₅ (g) ↔ PCl₃ (g) + Cl₂(g)

In terms of period and group where would you locate the element with Z =114?

Write the resonance structures for SO₃, NO₂ and .

Draw the resonance structures for the following compounds. Show the electron shift using curved-arrow notation.

(a) C₆H₅OH

(b) C₆H₅NO₂

(c) CH₃CH=CHCHO

(d) C₆H₅–CHO

(e) C₆ H₅ - C⁺H₂ 

(f)  CH₃CH = CHC⁺H₂

At 473 K, equilibrium constant K_c for decomposition of phosphorus pentachloride, PCl₅ is 8.3 ×10^-3. If decomposition is depicted as,

PCl₅ (g) ↔  PCl₃ (g) + Cl₂ (g)          Δ_rH⁰ = 124.0 kJ mol^–1

(a) write an expression for Kc for the reaction.

(b) what is the value of Kc for the reverse reaction at the same temperature ?

(c) what would be the effect on K_c if (i) more PCl5 is added (ii) pressure is increased (iii) the temperature is increased ?

Discuss the shape of the following molecules using the VSEPR model:

BeCl₂, BCl₃, SiCl₄, AsF₅, H₂S, PH₃

Which of the following reactions will get affected by increasing the pressure?

Also, mention whether change will cause the reaction to go into forward or backward direction.

(i) COCl₂ (g) ↔ CO (g) + Cl₂ (g)

(ii) CH₄ (g) + 2S₂ (g) ↔ CS₂ (g) + 2H₂S (g)

(iii) CO₂ (g) + C (s) ↔ 2CO (g)

(iv) 2H₂ (g) + CO (g) ↔ CH₃OH (g)

(v) CaCO₃ (s) ↔ CaO (s) + CO₂ (g)

(vi) 4 NH₃ (g) + 5O₂ (g) ↔ 4NO (g)  +  6H₂O(g)