Explain the significance of sodium, potassium, magnesium and calcium inbiological fluids.
Importance of sodium, potassium, magnesium, and calcium in biological fluids:
(i) Sodium (Na):
Sodium ions are found primarily in the blood plasma. They are also found in the interstitial fluids surrounding the cells.
(a) Sodium ions help in the transmission of nerve signals.
(b) They help in regulating the flow of water across the cell membranes.
(c) They also help in transporting sugars and amino acids into the cells.
(ii) Potassium (K):
Potassium ions are found in the highest quantity within the cell fluids.
(a) K ions help in activating many enzymes.
(b) They also participate in oxidising glucose to produce ATP.
(c) They also help in transmitting nerve signals.
(iii) Magnesium (Mg) and calcium (Ca):
Magnesium and calcium are referred to as macro-minerals. This term indicates their higher abundance in the human body system.
(a) Mg helps in relaxing nerves and muscles.
(b) Mg helps in building and strengthening bones.
(c) Mg maintains normal blood circulation in the human body system.
(d) Ca helps in the coagulation of blood
(e) Ca also helps in maintaining homeostasis.
Compare the alkali metals and alkaline earth metals with respect to
(i) ionization enthalpy
(ii) basicity of oxides and
(iii) solubility of hydroxides.
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals.
(a) Nitrates (b) Carbonates (c) Sulphates.
Discuss the various reactions that occur in the Solvay process.
Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) E° for M2+(aq) (where M = Ca, Sr or Ba) is nearly constant.
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
State as to why
(a) a solution of Na2CO3 is alkaline ?
(b) alkali metals are prepared by electrolysis of their fused chlorides ?
(c) sodium is found to be more useful than potassium ?
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
Why is Li2CO3 decomposed at a lower temperature whereas Na2CO3 at higher temperature?
In what ways lithium shows similarities to magnesium in its chemical behaviour?
Find the oxidation state of sodium in Na2O2.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for testing sulphur by lead acetate test?
Which element do you think would have been named by
(i) Lawrence Berkeley Laboratory
(ii) Seaborg’s group?
Nitrogen laser produces a radiation at a wavelength of 337.1 nm. If the number of photons emitted is 5.6 × 1024, calculate the power of this laser.
Which of the following pairs of elements would have a more negative electron gain enthalpy?
(i) O or F
(ii) F or Cl
The first ionization constant of H2S is 9.1 × 10–8. Calculate the concentration of HS– ion in its 0.1M solution. How will this concentration be affected if the solution is 0.1M in HCl also ? If the second dissociation constant of H2S is 1.2 × 10–13, calculate the concentration of S2– under both conditions.
Explain with the help of suitable example polar covalent bond.
Determine the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are 69.9 and 30.1 respectively. Given that the molar mass of the oxide is 159.69 g mol–1.
Explain structures of diborane and boric acid.
Explain, giving reasons, which of the following sets of quantum numbers are not possible.
a n = 0 l = 0 ml = 0
b n = 1 l = 0 ml = 0
c n = 1 l = 1 ml = 0
d n = 2 l = 1 ml = 0
e n = 3 l = 3 ml = – 3
f n = 3 l = 1 ml = 0
The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists:
1. n = 4, l = 2, ml = –2 , ms = –1/2
2. n = 3, l = 2, ml= 1 , ms = +1/2
3. n = 4, l = 1, ml = 0 , ms = +1/2
4. n = 3, l = 2, ml = –2 , ms = –1/2
5. n = 3, l = 1, ml = –1 , ms= +1/2
6. n = 4, l = 1, ml = 0 , ms = +1/2