How many neutrons and protons are there in the following nuclei?
We know atomic number(z) = no of protons = no of electrons
Also mass number(A) = no of protons + no of neutrons
136C:
Here mass number = 13
Atomic number = Number of protons = 6
Number of neutrons = (mass number) – (Atomic number)
= 13 – 6 = 7
:
Here mass number = 16
Atomic number = 8 Number of protons = 8 Number of neutrons = (mass number) – (Atomic number)
= 16 – 8 = 8
:
Here Mass number = 24
Atomic number = Number of protons = 12
Number of neutrons = (mass number) – (Atomic number)
= 24 – 12 = 12
:
Here mass number = 56
Atomic number = Number of protons = 26
Number of neutrons = (mass number ) – (Atomic number)
= 56 – 26 = 30
:
Here mass number = 88
Atomic number = Number of protons = 38
Number of neutrons = (mass number) – (Atomic number)
= 88 – 38 = 50
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Using the equation of state pV = nRT; show that at a given temperature density of a gas is proportional to gas pressurep.
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Draw the structure of (i) BeCl2 (vapour) (ii) BeCl2 (solid).
Write the expression for the equilibrium constant, Kc for each of the following reactions:
(i) 2NOCl (g) ↔ 2NO (g) + Cl2 (g)
(ii) 2Cu(NO3)2 (s) ↔ 2CuO (s) + 4NO2 (g) + O2 (g)
(iii) CH3COOC2H5(aq) + H2O(l) ↔ CH3COOH (aq) + C2H5OH (aq)
(iv) Fe3+ (aq) + 3OH– (aq) ↔ Fe(OH)3 (s)
(v) I2 (s) + 5F2 ↔ 2IF5
What are pesticides and herbicides? Explain giving examples.
A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
Convert the following into basic units:
(i) 28.7 pm
(ii) 15.15 pm
(iii) 25365 mg
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2, , HCOOH
Discuss the pattern of variation in the oxidation states of
(i) B to Tl and (ii) C to Pb.
Write the atomic number of the element present in the third period and seventeenth group of the periodic table.
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