Pressure of 1 g of an ideal gas A at 27 °C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at same temperature the pressure becomes 3 bar. Find a relationship between their molecular masses.
Mass of gas A , WA = 1g
Mass of gas B, WB = 2g
Pressure exerted by the gas A = 2 bar
Total pressure due to both the gases = 3 bar
In this case temperature & volume remain constant
Now if MA & MB are molar masses of the gases A & B respectively,therefore
pA V= WA RT/MA & Ptotal V = (WA/MA + WB/ MB) RT
= 2 X V = 1 X RT/MA & 3 X V = (1/MA + 2/MB)RT
From these two equations, we get
3/2 = (1/MA + 2/MB) / (1 /MA) = (MB + 2MA) / MB
This result in 2MA/ MB = (3/2) -1 = ½
OR MB = 4MA
Thus, a relationship between the molecular masses of A and B is given by
4MA = MB
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bar.
(R = 0.083 bar dm3 K–1 mol–1).
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
What would be the SI unit for the quantity pV2T 2/n?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals.
(a) Nitrates (b) Carbonates (c) Sulphates.
Give the number of electrons in the species , H2 and
Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) E° for M2+(aq) (where M = Ca, Sr or Ba) is nearly constant.
Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation:
N2(g) + H2(g) → 2NH3(g)
(i) Calculate the mass of ammonia produced if 2.00 × 103 g dinitrogen reacts with 1.00 × 103 g of dihydrogen.
(ii) Will any of the two reactants remain unreacted?
(iii) If yes, which one and what would be its mass?
Do you observe any soil pollution in your neighbourhood? What efforts will you make for controlling the soil pollution?
What do you understand by (i) electron-deficient, (ii) electron-precise, and (iii) electron-rich compounds of hydrogen? Provide justification with suitable examples.
Discuss the consequences of high enthalpy of H-H bond in terms of chemical reactivity of dihydrogen.
Predict which of the following reaction will have appreciable concentration of reactants and products:
a) Cl2 (g) ↔ 2Cl (g) Kc = 5 ×10–39
b) Cl2 (g) + 2NO (g) ↔ 2NOCl (g) Kc = 3.7 × 108
c) Cl2 (g) + 2NO2 (g) ↔ 2NO2Cl (g) Kc = 1.8
At 1127 K and 1 atm pressure, a gaseous mixture of CO and CO2 in equilibrium with soild carbon has 90.55% CO by mass
C (s) + CO2 (g) ↔ 2CO (g)
Calculate Kc for this reaction at the above temperature.
Explain, why an organic liquid vaporises at a temperature below its boiling point in its steam distillation?
Why it can't be just p directly proportional to molecular weight by which mw1=2mw2
Greatest explanation
Thank you. Really helpful ð
R is here universal gas constant
R is here universal gas constant
Why does the volume is constant here ... it is not given in question ..????
W means n
R means 0.281 atm
Anita are u know the formula of mAss\molarmass =n and here n is represented by W ðð
What is meaning of wA/mA+wB/mB in this question please answer