In terms of period and group where would you locate the element with Z =114?
Elements with atomic numbers from Z = 87 to Z = 114 are present in the 7th period of the periodic table. Thus, the element with Z = 114 (Flerovium) with atomic weight 289 and a poor metal is present in the 7th period and 14th group of the periodic table.
In the 7th period, first two elements with Z = 87 and Z= 88 are s-block elements, the next 14 elements excluding Z = 89 i.e., those with Z = 90 – 103 are f – block elements, ten elements with Z = 89 and Z = 104 – 112 are d – block elements, and the elements with Z = 113 – 118 are p – block elements. Therefore, the element with Z = 114 is the second p – block element in the 7th period.
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:
(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions.
(i) F–
(ii) Ar
(iii) Mg2+
(iv) Rb+
What is the basic difference between the terms electron gain enthalpy and electronegativity?
Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is:
(a) B > C > Si > N > F
b) Si > C > B > N > F
(c) F > N > C > B > Si
d) F > N > C > Si > B
Assign the position of the element having outer electronic configuration
(i) ns2 np4 for n = 3 (ii) (n - 1)d2 ns2 for n = 4, and (iii) (n - 2) f7 (n - 1)d1 ns2 for n = 6, in the periodic table.
How does atomic radius vary in a period and in a group? How do you explain the variation?
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is:
(a) F > Cl > O > N
(b) F > O > Cl > N
(c) Cl > F > O > N
(d) O > F > N > Cl
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
An ion with mass number 37 possesses one unit of negative charge. If the ion contains 11.1% more neutrons than the electrons, find the symbol of the ion.
The following data are obtained when dinitrogen and dioxygen react together to form different compounds:
Mass of dinitrogen Mass of dioxygen
(i) 14 g 16 g
(ii) 14 g 32 g
(iii) 28 g 32 g
(iv) 28 g 80 g
(a) Which law of chemical combination is obeyed by the above experimental data?Give its statement.
(b) Fill in the blanks in the following conversions:
(i) 1 km = ...................... mm = ...................... pm
(ii) 1 mg = ...................... kg = ...................... ng
(iii) 1 mL = ...................... L = ...................... dm3
The type of hybridisation of boron in diborane is
(a) sp (b) sp2 (c) sp3 (d) dsp2
0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.
Give the IUPAC names of the following compounds:
The solubility of Sr(OH)2 at 298 K is 19.23 g/L of solution. Calculate the concentrations of strontium and hydroxyl ions and the pH of the solution.
Use Lewis symbols to show electron transfer between the following atoms to form cations and anions:
(a) K and S (b) Ca and O (c) Al and N.
How many significant figures should be present in the answer of the following calculations?
(i)
(ii) 5 × 5.364
(iii) 0.0125 + 0.7864 + 0.0215
Suggest a reason as to why CO is poisonous.
Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
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