How many neutrons and protons are there in the following nuclei?
We know atomic number(z) = no of protons = no of electrons
Also mass number(A) = no of protons + no of neutrons
136C:
Here mass number = 13
Atomic number = Number of protons = 6
Number of neutrons = (mass number) – (Atomic number)
= 13 – 6 = 7
:
Here mass number = 16
Atomic number = 8 Number of protons = 8 Number of neutrons = (mass number) – (Atomic number)
= 16 – 8 = 8
:
Here Mass number = 24
Atomic number = Number of protons = 12
Number of neutrons = (mass number) – (Atomic number)
= 24 – 12 = 12
:
Here mass number = 56
Atomic number = Number of protons = 26
Number of neutrons = (mass number ) – (Atomic number)
= 56 – 26 = 30
:
Here mass number = 88
Atomic number = Number of protons = 38
Number of neutrons = (mass number) – (Atomic number)
= 88 – 38 = 50
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
Classify the following species into Lewis acids and Lewis bases and show how these act as Lewis acid/base:
(a) OH–
(b) F–
(c) H+
(d) BCl3
Differentiate between the principle of estimation of nitrogen in an organic compound by
(i) Dumas method and
(ii) Kjeldahl's method.
What are the major differences between metals and non-metals?
Give condensed and bond line structural formulas and identify the functional group(s) present, if any, for :
(a) 2,2,4-Trimethylpentane
(b) 2-Hydroxy-1,2,3-propanetricarboxylic acid
(c) Hexanedial
Rationalise the given statements and give chemical reactions :
(i) Lead(II) chloride reacts with Cl2 to give PbCl4.
(ii) Lead(IV) chloride is highly unstable towards heat.
(iii) Lead is known not to form an iodide, PbI4.
The first ionization constant of H2S is 9.1 × 10–8. Calculate the concentration of HS– ion in its 0.1M solution. How will this concentration be affected if the solution is 0.1M in HCl also ? If the second dissociation constant of H2S is 1.2 × 10–13, calculate the concentration of S2– under both conditions.
Explain why the following systems are not aromatic?
What happens when
(a) Borax is heated strongly,
(b) Boric acid is added to water,
(c) Aluminium is treated with dilute NaOH,
(d) BF3 is reacted with ammonia?
Although both CO2 and H2O are triatomic molecules, the shape of H2O molecule is bent while that of CO2 is linear. Explain this on the basis of dipole moment.
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