Class 11 Chemistry - Chapter Structure of Atom NCERT Solutions | An ion with mass number 56 contains 3 un

The mass of an electron is 9.1 × 10^–31 kg. If its K.E. is 3.0 × 10^–25 J, calculate its wavelength.

Calculate the wavelength of an electron moving with a velocity of 2.05 × 10⁷ ms^–1.

Using s, p, d notations, describe the orbital with the following quantum numbers.

(a) n = 1, l = 0;

(b) n = 3; l =1

(c) n = 4; l = 2;

(d) n = 4; l =3.

Which of the following are isoelectronic species i.e., those having the same number of electrons?

Na⁺, K⁺, Mg²⁺, Ca²⁺, S^2–, Ar

Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10^–10 s.

How many electrons in an atom may have the following quantum numbers?

(a) n = 4,

(b) n = 3, l = 0

Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.

Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.

Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.

A photon of wavelength 4 × 10^–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate

(i) the energy of the photon (eV),

(ii) the kinetic energy of the emission, and

(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10^–19 J).

How do you account for the formation of ethane during chlorination of methane?

What are hybridisation states of each carbon atom in the following compounds ?

(i) CH₂=C=O,

(ii) CH₃CH=CH₂,

(iii) (CH₃)₂CO,

(iv) CH₂=CHCN,

(v) C₆H₆

What will be the minimum pressure required to compress 500 dm³ of air at 1 bar to 200 dm³ at 30°C?

What are the common physical and chemical features of alkali metals?

Calculate the molecular mass of the following:
(i) H₂O
(ii) CO₂
(iii) CH₄

Assign oxidation number to the underlined elements in each of the following species:

(a) NaH₂PO₄

(b) NaHSO₄

(c) H₄P₂O₇

(d) K₂MnO₄

(e) CaO₂

(f) NaBH₄

(g) H₂S₂O₇

(h) KAl(SO₄)₂.12 H₂O

What is the basic theme of organisation in the periodic table?

Explain the formation of a chemical bond.

Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.

A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?

Which of the following represents the correct IUPAC name for the compounds concerned?
(a) 2,2-Dimethylpentane or 2-Dimethylpentane
(b) 2,4,7-Trimethyloctane or 2,5,7-Trimethyloctane
(c) 2-Chloro-4-methylpentane or 4-Chloro-2-methylpentane
(d) But-3-yn-1-ol or But-4-ol-1-yne

What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

(a)

(b)

(c)

Express the following in the scientific notation:
(i) 0.0048
(ii) 234,000
(iii) 8008
(iv) 500.0
(v) 6.0012

Calculate the number of atoms in each of the following

(i) 52 moles of Ar

(ii) 52 u of He

(iii) 52 g of He.

Calculate the entropy change in surroundings when 1.00 mol of H₂O(l) is formed under standard conditions. Δ_fH⁰ = –286 kJ mol^–1.

Which of the following statements related to the modern periodic table is incorrect?
(a) The p-block has 6 columns, because a maximum of 6 electrons can occupy all the orbitals in a p-shell.
(b) The d-block has 8 columns, because a maximum of 8 electrons can occupy all the orbitals in a d-subshell.
(c) Each block contains a number of columns equal to the number of electrons that can occupy that subshell.
(d) The block indicates value of azimuthal quantum number (l ) for the last subshell that received electrons in building up the electronic configuration.

Why do elements in the same group have similar physical and chemical properties?

A mixture of 1.57 mol of N₂, 1.92 mol of H₂ and 8.13 mol of NH₃ is introduced into a 20 L reaction vessel at 500 K. At this temperature, the equilibrium constant, K_c for the reaction N₂ (g) + 3H₂ (g) ↔ 2NH₃ (g) is 1.7 × 10².

Is the reaction mixture at equilibrium? If not, what is the direction of the net reaction?

Calculate the temperature of 4.0 mol of a gas occupying 5 dm³ at 3.32 bar.

(R = 0.083 bar dm³ K^–1 mol^–1).

Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per following endothermic reaction:

CH₄ (g) + H₂O (g) ↔ CO (g) + 3H₂ (g)

(a) Write as expression for Kp for the above reaction.

(b) How will the values of Kp and composition of equilibrium mixture be affected by

  (i) increasing the pressure

  (ii) increasing the temperature

  (iii) using a catalyst ?