Explain tropospheric pollution in 100 words.
Tropospheric pollution arises due to the presence of undesirable substances in the lowest layer of the atmosphere.
Oxides of Sulphur, nitrogen, carbon, and hydrocarbons are the major gaseous pollutants.
Oxides of Sulphur (SO2 and SO3) and nitrogen (NO2, NO) are produced after burning of fossil fuels (coal, automobile fuel). These oxides react with water in the presence of atmospheric oxygen to form nitric acid (HNO3) and sulphuric acid (H2SO4), which leads to the formation of 'Acid rain'.
Acid rain causes harm to agriculture, plants, and trees. Also leading to various respiratory ailments.
Hydrocarbons are carbon and hydrogen containing compounds that produces oxides of carbon during burning. Hydrocarbons are carcinogenic and their products are also major pollutants. Carbon monoxide (CO) is poisonous in nature as it reacts with the haemoglobin of blood, which can even result in death. Though carbon dioxide (CO2) is not toxic in nature, yet it contributes towards global warming by trapping the reflected Infrared rays. This results in the heating up of the Earth's atmosphere, thereby leading to the melting of icebergs and glaciers.
Particulates of smoke, dust, mist, and fume are harmful for human health as they are likely to block the nasal passage of a person, causing respiratory ailments. Smoke and fog combine to produce smog during a cool, humid day, thereby reducing visibility to a large extent. Photochemical smog is formed due to the presence of PAN, ozone, formaldehyde, and acrolein. It causes eye irritation, headaches, and chest pain. It also leads to the cracking of rubber and does damage to plants.
Carbon monoxide gas is more dangerous than carbon dioxide gas. Why?
What are the harmful effects of photochemical smog and how can they be controlled?
Write down the reactions involved during the formation of photochemical smog.
What are the reactions involved for ozone layer depletion in the stratosphere?
What would have happened if the greenhouse gases were totally missing in the earth's atmosphere? Discuss.
Statues and monuments in India are affected by acid rain. How?
What do you mean by green chemistry? How will it help decrease environmental pollution?
What is smog? How is classical smog different from photochemical smog?
What do you mean by ozone hole? What are its consequences?
A large number of fish are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish kill.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
At 1127 K and 1 atm pressure, a gaseous mixture of CO and CO2 in equilibrium with soild carbon has 90.55% CO by mass
C (s) + CO2 (g) ↔ 2CO (g)
Calculate Kc for this reaction at the above temperature.
What will be the conjugate bases for the Brönsted acids: HF, H2SO4 and HCO3?
The equilibrium constant for the following reaction is 1.6 ×105 at 1024K
H2(g) + Br2(g) ↔ 2HBr(g)
Find the equilibrium pressure of all gases if 10.0 bar of HBr is introduced into a sealed container at 1024K.
Is there any change in the hybridisation of B and N atoms as a result of the following reaction?
BF3 + NH3 → F3B.NH3
The equilibrium constant for a reaction is 10. What will be the value of ΔG0 ? R = 8.314 JK–1 mol–1, T = 300 K.
What is the SI unit of mass? How is it defined?
Identify the reagents shown in bold in the following equations as nucleophiles or electrophiles:
(a) CH3COOH + HO- → CH3COO- + H2O
(b) CH3COCH3 + C-N → (CH3)2 C (CN) (OH)
(c) C6H5 + CH3C+O → C6H5COCH3
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium 40% of water (by mass) reacts with CO according to the equation,
H2O (g) + CO (g) ↔ H2 (g) + CO2 (g)
Calculate the equilibrium constant for the reaction.
Which of the following represents the correct IUPAC name for the compounds concerned?
(a) 2,2-Dimethylpentane or 2-Dimethylpentane
(b) 2,4,7-Trimethyloctane or 2,5,7-Trimethyloctane
(c) 2-Chloro-4-methylpentane or 4-Chloro-2-methylpentane
(d) But-3-yn-1-ol or But-4-ol-1-yne
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