How many electrons in an atom may have the following quantum numbers?
(a) n = 4,
(b) n = 3, l = 0
Total number of electrons in an atom for a value of n = 2n2
a) Total no of electrons when n=4 ,then n= 2x42 = 32 & half of them have ms = -1/2
b) When n= 3, l=0 means 3s orbital which can have 2 electrons .
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Using s, p, d notations, describe the orbital with the following quantum numbers.
(a) n = 1, l = 0;
(b) n = 3; l =1
(c) n = 4; l = 2;
(d) n = 4; l =3.
Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
Calculate the wavelength, frequency and wave number of a light wave whose period is 2.0 × 10–10 s.
Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency (ν) and wave number () of the yellow light.
Indicate the number of unpaired electrons in: (a) P, (b) Si, (c) Cr, (d) Fe and (e) Kr.
Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen.
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
Find energy of each of the photons which
(i) correspond to light of frequency 3× 1015 Hz.
(ii) have wavelength of 0.50 Å.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Compare the structures of H2O and H2O2.
Which of the following reactions will get affected by increasing the pressure?
Also, mention whether change will cause the reaction to go into forward or backward direction.
(i) COCl2 (g) ↔ CO (g) + Cl2 (g)
(ii) CH4 (g) + 2S2 (g) ↔ CS2 (g) + 2H2S (g)
(iii) CO2 (g) + C (s) ↔ 2CO (g)
(iv) 2H2 (g) + CO (g) ↔ CH3OH (g)
(v) CaCO3 (s) ↔ CaO (s) + CO2 (g)
(vi) 4 NH3 (g) + 5O2 (g) ↔ 4NO (g) + 6H2O(g)
Pay load is defined as the difference between the mass of displaced air and the mass of the balloon. Calculate the pay load when a balloon of radius 10 m, mass 100 kg is filled with helium at 1.66 bar at 27°C. (Density of air = 1.2 kg m–3 and R = 0.083 bar dm3 K–1 mol–1).
The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very strong oxidizing agent. Why?
Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place, further show:
(i) which of the electrode is negatively charged,
(ii) the carriers of the current in the cell, and
(iii) individual reaction at each electrode.
Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?
One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium 40% of water (by mass) reacts with CO according to the equation,
H2O (g) + CO (g) ↔ H2 (g) + CO2 (g)
Calculate the equilibrium constant for the reaction.
Which of the following carbocation is most stable ?
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
Thnks u very much
Short Cort
Thanx for given me this solution
Can we write these exact answers in exam
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