Class 12 Chemistry - Chapter The p-Block Elements NCERT Solutions | What happens when PCl5 is heated?

Why is helium used in diving apparatus?

Why are pentahalides more covalent than trihalides?

Give the formula and describe the structure of a noble gas species which is isostructural with:

(i) ICl^-₄

(ii) IBr^-₂

(iii) BrO^-₃

Why is H₂O a liquid and H₂S a gas?

How is O₃ estimated quantitatively?

What happens when sulphur dioxide is passed through an aqueous solution of Fe(III) salt?

Why is BiH3 the strongest reducing agent amongst all the hydrides of Group 15 elements?

Why are halogens strong oxidising agents?

Arrange the following in the order of property indicated for each set:

(i) F₂, Cl₂, Br₂, I₂- increasing bond dissociation enthalpy.

(ii) HF, HCl, HBr, HI - increasing acid strength.

(iii) NH₃, PH₃, AsH₃, SbH₃, BiH₃- increasing base strength.

Comment on the nature of two S-O bonds formed in SO₂ molecule. Are the two S-O bonds in this molecule equal?

For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.

Write the formulas for the following coordination compounds:

(i) Tetraamminediaquacobalt (III) chloride

(ii) Potassium tetracyanonickelate(II)

(iii) Tris(ethane-1,2-diamine) chromium(III) chloride

(iv) Amminebromidochloridonitrito-N-platinate(II)

(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate

(vi) Iron(III) hexacyanoferrate(II)

(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N

(ii) Write IUPAC names of all the isomers.

(iii) What type of isomerism is exhibited by different pairs of amines?

Why are solids rigid?

Write any two characteristics of Chemisorption.

Write the structures of the following compounds.

(i) α-Methoxypropionaldehyde

(ii) 3-Hydroxybutanal

(iii) 2-Hydroxycyclopentane carbaldehyde

(iv) 4-Oxopentanal

(v) Di-sec-butyl ketone

(vi) 4-Fluoroacetophenone

Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?

Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?

Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.

Write structures of the following compounds:

(i) 2-Chloro-3-methylpentane

(ii) 1-Chloro-4-ethylcyclohexane

(iii) 4-tert. Butyl-3-iodoheptane

(iv) 1,4-Dibromobut-2-ene

(v) 1-Bromo-4-sec. butyl-2-methylbenzene

Explain the cleansing action of soaps.

Calculate the mass of a non-volatile solute (molar mass 40 g mol^-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

What are inner transition elements? Decide which of the following atomic numbers are the atomic numbers of the inner transition elements: 29, 59, 74, 95, 102, 104.

Action of soap is due to emulsification and micelle formation. Comment.

Write the structures of the following organic halogen compounds.

(i) 2-Chloro-3-methylpentane

(ii) p-Bromochlorobenzene

(iii) 1-Chloro-4-ethylcyclohexane

(iv) 2-(2-Chlorophenyl)-1-iodooctane

(v) Perfluorobenzene

(vi) 4-tert-Butyl-3-iodoheptane

(vii) 1-Bromo-4-sec-butyl-2-methylbenzene

(viii) 1,4-Dibromobut-2-ene

Write the Nernst equation and emf of the following cells at 298 K:

(i) Mg(s) | Mg²⁺(0.001M) || Cu²⁺(0.0001 M) | Cu(s)

(ii) Fe(s) | Fe²⁺(0.001M) || H⁺(1M)|H₂(g)(1bar) | Pt(s)

(iii) Sn(s) | Sn²⁺(0.050 M) || H⁺(0.020 M) | H₂(g) (1 bar) | Pt(s)

(iv) Pt(s) | Br₂(l) | Br^-(0.010 M) || H⁺(0.030 M) | H₂(g) (1 bar) | Pt(s).

Draw figure to show the splitting of d orbitals in an octahedral crystal field.

Which forces are involved in holding the drugs to the active site of enzymes ?

How would you account for the following:

(i) Of the d⁴ species, Cr²⁺ is strongly reducing while manganese (III) is strongly oxidising.

(ii) Cobalt (II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidised.

(iii) The d¹ configuration is very unstable in ions.

Calculate the depression in the freezing point of water when 10 g of CH₃CH₂CHClCOOH is added to 250 g of water. K_a = 1.4 x 10^-3, K_f = 1.86 K kg mol^-1.