Class 11 Chemistry - Chapter The p Block Elements NCERT Solutions | Aluminium trifluoride is insoluble in an
Aluminium trifluoride is insoluble in anhydrous HF but dissolves on addition of NaF. Aluminium trifluoride precipitates out of the resulting solution when gaseous BF3 is bubbled through. Give reasons.
Hydrogen fluoride (HF) is a covalent compound and has very strong intermolecular hydrogen-bonding. Thus, it does not provide ions and aluminium fluoride (AlF) does not dissolve in it. Sodium fluoride (NaF) is an ionic compound and when it is added to the mixture, AlF dissolves. This is because of the availability of free F-. The reaction involved in the process is:
AlF3 + 3 NaF → Na3[AIF6]
Sodium hexafluoroaluminate(lll)
When boron trifluoride (BF3) is added to the solution, aluminium fluoride precipitates out of the solution. This happens because tendency of boron to form complexes is much more than that of aluminium. Therefore, when BF3 is added to the solution, B replaces Al from the complexes according to the following reaction:
Na3[AIF6] + 3 BF3 → 3 Na[BF4] + AlF3
More Questions From Class 11 Chemistry - Chapter The p Block Elements
- Q:-
What happens when
(a) Borax is heated strongly,
(b) Boric acid is added to water,
(c) Aluminium is treated with dilute NaOH,
(d) BF3 is reacted with ammonia?
- Q:-
Give reasons:
(i) Conc. HNO3 can be transported in aluminium container.
(ii) A mixture of dilute NaOH and aluminium pieces is used to open drain.
(iii) Graphite is used as lubricant.
(iv) Diamond is used as an abrasive.
(v) Aluminium alloys are used to make aircraft body.
(vi) Aluminium utensils should not be kept in water overnight.
(vii) Aluminium wire is used to make transmission cables.
- Q:-
Write reactions to justify amphoteric nature of aluminium.
- Q:-
Why does boron trifluoride behave as a Lewis acid?
- Q:-
Discuss the pattern of variation in the oxidation states of
(i) B to Tl and (ii) C to Pb. - Q:-
Write balanced equations for:
(i) BF3 + LiH →
(ii) B2H6 + H2O →
(iii) NaH + B2H6 →
(iv) H3BO3
(v) Al + NaOH →
(vi) B2H6 + NH3 →
- Q:-
How can you explain higher stability of BCl3 as compared to TlCl3?
- Q:-
A certain salt X, gives the following results.
(i) Its aqueous solution is alkaline to litmus.
(ii) It swells up to a glassy material Yon strong heating.
(iii) When conc. H2SO4 is added to a hot solution of X, white crystal of an acid Z separates out.
Write equations for all the above reactions and identify X, Y and Z.
- Q:-
(a) Classify following oxides as neutral, acidic, basic or amphoteric:
CO, B2O3, SiO2, CO2, Al2O3, PbO2, Tl2O3
(b) Write suitable chemical equations to show their nature.
- Q:-
Rationalise the given statements and give chemical reactions :
(i) Lead(II) chloride reacts with Cl2 to give PbCl4.
(ii) Lead(IV) chloride is highly unstable towards heat.
(iii) Lead is known not to form an iodide, PbI4.
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(iv) CH2=CHCN,
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(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
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(f) NaBH4
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- Q:-
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(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only. - Q:-
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
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