Give reasons:
(i) Conc. HNO3 can be transported in aluminium container.
(ii) A mixture of dilute NaOH and aluminium pieces is used to open drain.
(iii) Graphite is used as lubricant.
(iv) Diamond is used as an abrasive.
(v) Aluminium alloys are used to make aircraft body.
(vi) Aluminium utensils should not be kept in water overnight.
(vii) Aluminium wire is used to make transmission cables.
(i) Concentrated HNO3 can be stored and transported in aluminium containers as it reacts with aluminium to form a thin protective oxide layer on the aluminium surface. This oxide layer renders aluminium passive.
(ii) Sodium hydroxide and aluminium react to form sodium tetrahydroxoaluminate(III) and hydrogen gas. The pressure of the produced hydrogen gas is used to open blocked drains.
2Al + 2NaOH + 6H2O → 2Na+[Al(OH)4]- + 3H2
(iii) Graphite has layered structure and different layers of graphite are bonded to each other by weak van der Waals' forces. These layers can slide over each other. Graphite is soft and slippery. Therefore, graphite can be used as a lubricant.
(iv) In diamond, carbon is sp3 hybridised. Each carbon atom is bonded to four other carbon atoms with the help of strong covalent bonds. These covalent bonds are present throughout the surface, giving it a very rigid 3-D structure. It is very difficult to break this extended covalent bonding and for this reason, diamond is the hardest substance. Thus, it is used as an abrasive and for cutting tools.
(v) Aluminium has a high tensile strength and is very light in weight. It can also be alloyed with various metals such as Cu, Mn, Mg, Si, and Zn. It is very malleable and ductile. Therefore, it is used in making aircraft bodies.
(vi) The oxygen present in water reacts with aluminium to form thin layer of aluminium oxide. This layer prevents aluminium from further reaction. However, when water is kept in an aluminium vessel for long periods of time, some amount of aluminium oxide may dissolve in water. As aluminium ions are harmful, water should not be stored in aluminium vessels overnight.
(vii) Silver, copper, and aluminium are among the best conductors of electricity. Silver is an expensive metal and silver wires are very expensive. Copper is quite expensive and is also very heavy. Aluminium is very ductile metal. Thus, aluminium is used in making wires for electrical conduction.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium the partial pressure of HI(g) is 0.04 atm. What is Kp for the given equilibrium ?
2HI (g) ↔ H2 (g) + I2 (g)
For the process to occur under adiabatic conditions, the correct condition is:
(i) ΔT = 0
(ii) Δp = 0
(iii) q = 0
(iv) w = 0
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
Explain the significance of sodium, potassium, magnesium and calcium inbiological fluids.
Which one of the alkaline earth metal carbonates is thermally the most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Does the number of moles of reaction products increase, decrease or remain same when each of the following equilibria is subjected to a decrease in pressure by increasing the volume?
(a) PCl5 (g) ↔ PCl3 (g) + Cl2 (g)
(b) CaO (s) + CO2 (g) ↔ CaCO3 (s)
(c) 3Fe (s) + 4H2O (g) ↔ Fe3O4 (s) + 4H2 (g)
Use molecular orbital theory to explain why the Be2 molecule does not exist.