Classify the following into monosaccharides and disaccharides.
Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose
Monosaccharides:
Ribose, 2-deoxyribose, galactose, fructose
Disaccharides:
Maltose, lactose
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
What are nucleic acids? Mention their two important functions.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
What is meant by positive & negative deviations from raoult’s law & how is the sign of ΔmixH related to positive & negative deviations from Raoult’s law?
If the solubility product of CuS is 6 x 10-16, calculate the maximum molarity of CuS in aqueous solution.
Why is zinc not extracted from zinc oxide through reduction using CO?
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Indicate the steps in the preparation of:
(i) K2Cr2O7 from chromite ore.
(ii) KMnO4 from pyrolusite ore.
What are ambident nucleophiles? Explain with an example.
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
How does the presence of double bonds in rubber molecules influence their structure and reactivity?
Is ( NH — CHR — CO )n a homopolymer or copolymer?
Classify each of the following solids as ionic, metallic, molecular, network (covalent) or amorphous.
(i) Tetra phosphorus decoxide (P4O10) (vi) Plastic
(ii) Ammonium phosphate (NH4)3PO4 (vii) Graphite
(iii) SiC (viii) Brass
(iv) I2 (ix) Rb
(v) P4 (x) LiBr
(xi) Si