What is the basic structural difference between starch and cellulose?
Starch consists of two components - amylose and amylopectin. Amylose is a long linear chain of ∝-D-(+)-glucose units joined by C1-C4 glycosidic linkage (∝-link).
Amylopectin is a branched-chain polymer of ∝-D-glucose units, in which the chain is formed by C1-C4 glycosidic linkage and the branching occurs by C1-C6 glycosidic linkage.
On the other hand, cellulose is a straight-chain polysaccharide of β-D-glucose units joined by C1-C4 glycosidic linkage (β-link).
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
What are nucleic acids? Mention their two important functions.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Differentiate between "minerals" and "ores".
Explain why Cu+ ion is not stable in aqueous solutions?
How much electricity in terms of Faraday is required to produce
(i) 20.0 g of Ca from molten CaCl2.
(ii) 40.0 g of Al from molten Al2O3.
Explain why propanol has higher boiling point than that of the hydrocarbon, butane?
From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.
(i) 3 NO(g) → N2O(g) Rate = k[NO]2
(ii) H2O2 (aq) + 3 I - (aq) + 2 H+→ 2 H2O (l) + I3- Rate = k[H2O2][I - ]
(iii) CH3CHO(g) → CH4(g) + CO(g) Rate = k [CH3CHO]3/2
(iv) C2H5Cl(g) → C2H4(g) + HCl(g) Rate = k [C2H5Cl]
Why are halogens coloured?
With what neutral molecule is ClO- isoelectronic? Is that molecule a Lewis base?
What is meant by unidentate, didentate and ambidentate ligands? Give two examples for each.
What role does the molecular interaction play in a solution of alcohol and water?
Vapour pressure of water at 293 Kis 17.535 mm Hg. Calculate the vapour pressure of water at 293 Kwhen 25 g of glucose is dissolved in 450 g of water.
It's nice and precise to the point
Structural difference between starch and cellulose.