Differentiate between globular and fibrous proteins.
Fibrous protein |
Globular protein |
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1. |
It is a fibre-like structure formed by the polypeptide chain. These proteins are held together by strong hydrogen and disulphide bonds. |
1. |
The polypeptide chain in this protein is folded around itself, giving rise to a spherical structure. |
2. |
It is usually insoluble in water. |
2. |
It is usually soluble in water. |
3. 4. 5. |
Fibrous proteins are usually used for structural purposes. For example, keratin is present in nails and hair; collagen in tendons; and myosin in muscles. Fibrous proteins are made up of regular amino acid proteins. Fibrous proteins are less sensitive to any changes in pH or temperature.
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3. 4. 5. |
All enzymes are globular proteins. Some hormones such as insulin are also globular proteins. The amino acid sequece is irregular in globular proteins. Globular proteins are sensitive to any changes in pH, temperature etc. |
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
What are nucleic acids? Mention their two important functions.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complexes:
(i) K3[Co(C2O4)3]
(ii) cis-[Cr(en)2Cl2]Cl
(iii) (NH4)2[CoF4]
(iv) [Mn(H2O)6]SO4
In terms of band theory, what is the difference
(i) Between a conductor and an insulator
(ii) Between a conductor and a semiconductor
The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.
Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 x 10-3m aqueous solution required for the above dose.
Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon tetrachloride.
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:
1) Molar mass of the solute
2) Vapour pressure of water at 298 K.
The activation energy for the reaction 2HI(g) → H2 + I2(g) is 209.5 kJ mol-1 at 581 K. Calculate the fraction of molecules of reactants having energy equal to or greater than activation energy?
What is the role of depressant in froth floatation process?
What is an adsorption isotherm? Describe Freundlich adsorption isotherm.