Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
Polymer |
Monomer |
Structure of monomer |
|
i |
Buna-S |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Styrene |
C6H5CH = CH2 |
||
ii |
Buna-N |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Acrylonitrile |
CH2 = CH – CN |
||
iii |
Neoprene |
Chloroprene |
|
iv |
Dacron |
Ethylene glycol |
HOH2C –CH2OH |
Terephthalic acid |
|
1) Buna-S (styrene butadiene rubber) - It is obtained by the polymerization of Buta-1, 3 -diene and styrene in the ratio of 3:1 in the presence of sodium. It is used for making automobile tyres and footwear.
2) Buna-N (Nitrile rubber)- It is obtained by polymerization of 1,3-butadiene and acrylonitrile in the presence of a peroxide catalyst. It is used for making oil seals, manufacture of hoses and tank linings.
3) Dacron – It is obtained by the polymerization of ethylene glycol and terphthalic acid.
4) Neoprene –It is prepared by the free radical polymerization of chloroprene. It is used as insulator, for making belts, gaskets, hoses etc.
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
How are polymers classified on the basis of structure?
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
What are the monomeric repeating units of Nylon-6 and Nylon-6, 6?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Explain giving reasons:
(i) Transition metals and many of their compounds show paramagnetic behaviour.
(ii) The enthalpies of atomisation of the transition metals are high.
(iii) The transition metals generally form coloured compounds.
(iv) Transition metals and their many compounds act as good catalyst.
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
Explain why Cu+ ion is not stable in aqueous solutions?
Explain with two examples each of the following: coordination entity, ligand, coordination number, coordination polyhedron, homoleptic and heteroleptic.
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present ?
Explain the following with an example.
(i) Kolbe's reaction.
(ii) Reimer-Tiemann reaction.
(iii) Williamson ether synthesis.
(iv) Unsymmetrical ether.
(i) What is meant by the term 'coordination number'?
(ii) What is the coordination number of atoms:
(a) in a cubic close-packed structure?
(b) in a body-centred cubic structure?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Analysis shows that nickel oxide has the formula Ni0.98 O1.00. What fractions of nickel exist as Ni2+and Ni3+ions?
An organic compound with the molecular formula C9H10O forms 2, 4-DNP derivative, reduces Tollens' reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1, 2-benzenedicarboxylic acid. Identify the compound.
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What are the monomer repeating units of nylon-6 and nylon-6,6
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