Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
Polymer |
Monomer |
Structure of monomer |
|
i |
Buna-S |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Styrene |
C6H5CH = CH2 |
||
ii |
Buna-N |
1, 3-butadiene |
CH2 = CH – CH = CH2 |
Acrylonitrile |
CH2 = CH – CN |
||
iii |
Neoprene |
Chloroprene |
|
iv |
Dacron |
Ethylene glycol |
HOH2C –CH2OH |
Terephthalic acid |
|
1) Buna-S (styrene butadiene rubber) - It is obtained by the polymerization of Buta-1, 3 -diene and styrene in the ratio of 3:1 in the presence of sodium. It is used for making automobile tyres and footwear.
2) Buna-N (Nitrile rubber)- It is obtained by polymerization of 1,3-butadiene and acrylonitrile in the presence of a peroxide catalyst. It is used for making oil seals, manufacture of hoses and tank linings.
3) Dacron – It is obtained by the polymerization of ethylene glycol and terphthalic acid.
4) Neoprene –It is prepared by the free radical polymerization of chloroprene. It is used as insulator, for making belts, gaskets, hoses etc.
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
How are polymers classified on the basis of structure?
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
What are the monomeric repeating units of Nylon-6 and Nylon-6, 6?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write the conditions to maximize the yield of H2SO4 by Contact process.
Sleeping pills are recommended by doctors to the patients suffering from sleeplessness but it is not advisable to take its doses without consultation with the doctor, Why?
Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What kind of solid solution is this likely to be?
Low level of noradrenaline is the cause of depression. What type of drugs are needed to cure this problem ? Name two drugs.
Why is N2 less reactive at room temperature?
Mention the conditions required to maximise the yield of ammonia.
How is 'cast iron' different from 'pig iron"?
Write structures of the compounds whose IUPAC names are as follows:
(i) 2-Methylbutan-2-ol
(ii) 1-Phenylpropan-2-ol
(iii) 3,5-Dimethylhexane -1, 3, 5-triol
(iv) 2,3 - Diethylphenol
(v) 1 - Ethoxypropane
(vi) 2-Ethoxy-3-methylpentane
(vii) Cyclohexylmethanol
(viii) 3-Cyclohexylpentan-3-ol
(ix) Cyclopent-3-en-1-ol
(x) 3-Chloromethylpentan-1-ol.
Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following points:
(i) electronic configurations,
(ii) oxidation states,
(iii) ionisation enthalpies, and
(iv) atomic sizes.
Explain why
(i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?
(ii) alkyl halides, though polar, are immiscible with water?
(iii) Grignard reagents should be prepared under anhydrous conditions?
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What are the monomer repeating units of nylon-6 and nylon-6,6
AZAAB
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proved beneficial to me.. thnx 4 giving glimpse of monomers of polymers....
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