How are polymers classified on the basis of structure?
Polymers are classified on the basis of structure as follows:
1. Linear polymers: These polymers are formed of long straight chains. They can be depicted as:
For e.g., high density polythene (HDP), polyvinyl chloride, etc.
2. Branched chain polymers: These polymers are basically linear chain polymers with some branches. These polymers are represented as:
For e.g., low density polythene (LDP), amylopectin, etc.
3. Cross-linked or Network polymers: These polymers have many cross-linking bonds that give rise to a network-like structure. These polymers contain bi-functional and tri-functional monomers and strong covalent bonds between various linear polymer chains. Examples of such polymers include bakelite and melmac.
Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N
(iii) Dacron (iv) Neoprene
What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
Arrange the following polymers in increasing order of their intermolecular forces.
(i) Nylon 6, 6, Buna-S, Polythene.
(ii) Nylon 6, Neoprene, Polyvinyl chloride.
Explain the difference between Buna-N and Buna-S.
Define thermoplastics and thermosetting polymers with two examples of each.
Explain the term copolymerisation and give two examples.
Write the monomers used for getting the following polymers. (i) Polyvinyl chloride (ii) Teflon (iii) Bakelite
How do you explain the functionality of a monomer?
Identify the monomer in the following polymeric structures.
(i)
(ii)
What are the monomeric repeating units of Nylon-6 and Nylon-6, 6?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Classify the following amines as primary, secondary or tertiary:
(i)
(ii)
(iii) (C2H5)2CHNH2
(iv) (C2H5)2NH
Classify the following into monosaccharides and disaccharides.
Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose
Suggest the most important type of intermolecular attractive interaction in the following pairs.
(i) n-hexane and n-octane
(ii) I2 and CCl4
(iii) NaClO4 and water
(iv) methanol and acetone
(v) acetonitrile (CH3CN) and acetone (C3H6O).
Time required to decompose SO2Cl2to half of its initial amount is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.
What is lanthanoid contraction? What are the consequences of lanthanoid contraction?
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
Bond angle in PH+4 is higher than that in PH3. Why?
Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O.
Predict conditions under which Al might be expected to reduce MgO.
Write the reactions of F2 and Cl2 with water.
simple and clear
Density order