Complete the following chemical reactions.
(i) PbS(s) + H2O2(aq) →
(ii) MnO-4(aq) + H2O2(aq) →
(iii) CaO(s) + H2O(g) →
(iv) AlCl3(g) + H2O(I) →
(v) Ca3N2(s) + H2O(I) →
Classify the above into (a) hydrolysis, (b) redox and (c) hydration reactions.
(i) PbS(s) + H2O2(aq) → PbSO4(s) + H2O(l)
H2O2 is acting as an oxidizing agent in the reaction. Hence, it is a redox reaction.
(ii) 2MnO-4(aq) + 5H2O2(aq) → 6H+(aq) → 2Mn2+(aq) + 8H2O(l) + 5O2(g)
H2O2(aq) is acting as a reducing agent in the acidic medium, thereby oxidizing MnO-4(aq). Hence, the given reaction is a redox reaction.
(iii) CaO(s) + H2O(g) → Ca(OH)2aq
The reactions in which a compound reacts with water to produce other compounds are called hydrolysis reactions. The given reaction is hydrolysis.
(iv) 2AlCl3(g) + 3H2O(I) → Al2O3(s) + 6HCl(aq)
The reactions in which a compound reacts with water to produce other compounds are called hydrolysis reactions. The given reaction represents hydrolysis of AlCl3.
(v) Ca3N2(s) + 6H2O(I) → 3Ca(OH)2(aq) + 2NH3(g)
The reactions in which a compound reacts with water to produce other compounds are called hydrolysis reactions. The given reaction represents hydrolysis of Ca3N2.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same reaction yields 1-bromopropane. Explain and give mechanism.
What is the basic difference between the terms electron gain enthalpy and electronegativity?
If ten volumes of dihydrogen gas react with five volumes of dioxygen gas, how many volumes of water vapour would be produced?
Write down the reactions involved during the formation of photochemical smog.
How do you expect the metallic hydrides to be useful for hydrogen storage? Explain.
Find the oxidation state of sodium in Na2O2.
Use the data given in the following table to calculate the molar mass of naturally occurring argon isotopes:
Isotope |
Isotopic molar mass |
Abundance |
36Ar |
35.96755 gmol–1 |
0.337% |
38Ar |
37.96272 gmol–1 |
0.063% |
40Ar |
39.9624 gmol–1 |
99.600% |
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Define octet rule. Write its significance and limitations.
What is Kc for the following equilibrium when the equilibrium concentration of each substance is: [SO2]= 0.60 M, [O2] = 0.82 M and [SO3] = 1.90 M ?
2SO2(g) + O2(g) ↔ 2SO3(g)