Using the equation of state pV = nRT; show that at a given temperature density of a gas is proportional to gas pressurep.
The equation of state is given by, pV = nRT ……….. (i)
Where, p → Pressure of gas
V → Volume of gas
n→ Number of moles of gas
R → Gas constant
T → Temperature of gas
From equation (i) we have,
p = n RT/V
Where n= Mass of gas(m)/ Molar mass of gas(M)
Putting value of n in the equation, we have
p = m RT/ MV ------------(ii)
Now density(ρ) = m /V ----------------(iii)
Putting (iii) in (ii) we get
P = ρ RT / M
OR
ρ = PM / RT
Hence, at a given temperature, the density (ρ) of gas is proportional to its pressure (P)
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bar.
(R = 0.083 bar dm3 K–1 mol–1).
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure.
R = 0.083 bar L K–1 mol–1.
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. What is the molar mass of phosphorus?
2.9 g of a gas at 95 °C occupied the same volume as 0.184 g of dihydrogen at 17 °C, at the same pressure. What is the molar mass of the gas?
What would be the SI unit for the quantity pV2T 2/n?
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Explain the formation of a chemical bond.
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the following reactions:
(a) 2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)
(b) HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH-(aq) → 2Ag(s) + HCOO-(aq) + 4NH3(aq) + 2H2O(l)
(c) HCHO (l) + 2Cu2+(aq) + 5 OH-(aq) → Cu2O(s) + HCOO-(aq) + 3H2O(l)
(d) N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)
(e) Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)
Suggest a reason as to why CO is poisonous.
Pressure is determined as force per unit area of the surface. The SI unit of pressure, Pascal is as shown below:
1Pa = 1N m–2
If mass of air at sea level is 1034 g cm–2, calculate the pressure in Pascal.
Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% dioxygen by mass.
Give the number of electrons in the species , H2 and
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Given
N2(g) + 3H2(g) → 2NH3(g) ; ΔrH0 = –92.4 kJ mol–1
What is the standard enthalpy of formation of NH3 gas?
Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction,
CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?
In three moles of ethane (C2H6), calculate the following:
(i) Number of moles of carbon atoms.
(ii) Number of moles of hydrogen atoms.
(iii) Number of molecules of ethane.
(i) Calculate the total number of electrons present in one mole of methane.
(ii) Find
(a) the total number and
(b) the total mass of neutrons in 7 mg of 14C. (Assume that mass of a neutron = 1.675 × 10–27 kg).
(iii) Find
(a) the total number and
(b) the total mass of protons in 34 mg of NH3 at STP.
Will the answer change if the temperature and pressure are chang
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