Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
The stability of following species can be decided on the basis of bond order as follows:
O2 : KK
Bond order =1/2(Nb-Na)
= 1/2(8-4)
= 2 = Paramagnetic
Similarly, the electronic configuration of O2+ can be written as:
Bond order of O2+ = 1/2(8-3)
= 2.5 = paramagnetic
Electronic configuration of O2- ion will be:
Bond order of = 1/2(8-5)
= 1.5 = paramagnetic
Electronic configuration of O22- ion will be:
Bond order of O22- =1/2(8-6) = 1 diamagnetic
The larger the bond order,greater is the stability
Therefore the stability decreases as O2+ > O2 > O2- > O22-.
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Describe the change in hybridisation (if any) of the Al atom in the following reaction.
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2, , HCOOH
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Why are potassium and cesium, rather than lithium used in photoelectric cells?
A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate
(i) the energy of the photon (eV),
(ii) the kinetic energy of the emission, and
(iii) the velocity of the photoelectron (1 eV= 1.6020 × 10–19 J).
Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural formula of the alkene?
Symbols can be written, whereas symbols
are not acceptable. Answer briefly.
The hydroxides and carbonates of sodium and potassium are easily soluble in water while the corresponding salts of magnesium and calcium are sparingly soluble in water. Explain.
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Suggest reasons why the B-F bond lengths in BF3 (130 pm) and BF-4(143 pm) differ.
Pressure is determined as force per unit area of the surface. The SI unit of pressure, Pascal is as shown below:
1Pa = 1N m–2
If mass of air at sea level is 1034 g cm–2, calculate the pressure in Pascal.
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Whats KK ?
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How to identify para or dia magnet ic
WASTE
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