Class 12 Chemistry - Chapter The Solid State NCERT Solutions | Analysis shows that nickel oxide has the

If NaCl is doped with 10^-3mol % of SrCl₂, what is the concentration of cation vacancies?

A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?

An element with molar mass 2.7 x 10^-2kg mol^-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7 x 10³ kg m^-3, what is the nature of the cubic unit cell?

Copper crystallises into a fcc lattice with edge length 3.61 x 10^-8cm. Show that the calculated density is in agreement with its measured value of 8.92 g cm^-3.

A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3^rd of tetrahedral voids. What is the formula of the compound?

Aluminium crystallises in a cubic close-packed structure. Its metallic radius is 125 pm.

(i) What is the length of the side of the unit cell?

(ii) How many unit cells are there in 1.00 cm3of aluminium?

Distinguish between

(i)Hexagonal and monoclinic unit cells

(ii) Face-centred and end-centred unit cells.

Solid A is a very hard electrical insulator in solid as well as in molten state and melts at extremely high temperature. What type of solid is it?

Ionic solids, which have anionic vacancies due to metal excess defect, develop colour. Explain with the help of a suitable example.

How will you distinguish between the following pairs of terms:

(i) Hexagonal close-packing and cubic close-packing?

(ii) Crystal lattice and unit cell?

(iii) Tetrahedral void and octahedral void?

For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.

Write the formulas for the following coordination compounds:

(i) Tetraamminediaquacobalt (III) chloride

(ii) Potassium tetracyanonickelate(II)

(iii) Tris(ethane-1,2-diamine) chromium(III) chloride

(iv) Amminebromidochloridonitrito-N-platinate(II)

(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate

(vi) Iron(III) hexacyanoferrate(II)

(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N

(ii) Write IUPAC names of all the isomers.

(iii) What type of isomerism is exhibited by different pairs of amines?

Write any two characteristics of Chemisorption.

Write the structures of the following compounds.

(i) α-Methoxypropionaldehyde

(ii) 3-Hydroxybutanal

(iii) 2-Hydroxycyclopentane carbaldehyde

(iv) 4-Oxopentanal

(v) Di-sec-butyl ketone

(vi) 4-Fluoroacetophenone

Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?

Why are pentahalides more covalent than trihalides?

Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?

Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.

Write structures of the following compounds:

(i) 2-Chloro-3-methylpentane

(ii) 1-Chloro-4-ethylcyclohexane

(iii) 4-tert. Butyl-3-iodoheptane

(iv) 1,4-Dibromobut-2-ene

(v) 1-Bromo-4-sec. butyl-2-methylbenzene

Discuss the general characteristics of Group 15 elements with reference to their electronic configuration, oxidation state, atomic size, ionisation enthalpy and electronegativity.

Why is BiH3 the strongest reducing agent amongst all the hydrides of Group 15 elements?

Explain why

(i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?

(ii) alkyl halides, though polar, are immiscible with water?

(iii) Grignard reagents should be prepared under anhydrous conditions?

[NiCl₄]^2- is paramagnetic while [Ni(CO)₄] is diamagnetic though both are tetrahedral. Why?

Give the uses of freon 12, DDT, carbon tetrachloride and iodoform.

With reference to which classification has the statement, ranitidine is an antacid been given?

How will you bring about the following conversions?

(i) Ethanol to but-1-yne

(ii) Ethane to bromoethene

(iii) Propene to 1-nitropropane

(iv) Toluene to benzyl alcohol

(v) Propene to propyne

(vi) Ethanol to ethyl fluoride

(vii) Bromomethane to propanone

(viii) But-1-ene to but-2-ene

(ix) 1-Chlorobutane to n-octane

(x) Benzene to biphenyl.

Classify the following as addition and condensation polymers: Terylene, Bakelite, Polyvinyl chloride, Polythene.

An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?

Give the IUPAC names of the following compounds:

(i) CH₃CH(Cl)CH(Br)CH₃

(ii) CHF₂CBrClF

(iii) ClCH₂C≡CCH₂Br

(iv) (CCl₃)₃CCl

(v) CH₃C(p-ClC₆H₄)₂CH(Br)CH₃

(vi) (CH₃)₃CCH=CClC₆H₄I-p