One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10-10 m
Volume of hydrogen atom = 4/3 π r3
= 4/3 x 22/7 x (0.5 x 10-10)3
= 0.524 x 1030 m3
1 mole of hydrogen contains 6.023 × 1023 hydrogen atoms.
∴ Volume of 1 mole of hydrogen atoms = 6.023 × 1023 × 0.524 × 10-30
= 3.16 × 10-7 m3
Molar volume of 1 mole of hydrogen atoms at STP,
Vm = 22.4 L = 22.4 × 10-3 m3
∴ Vm / Va = 22.4 x 10-3 / 3.16 × 10-7 = 7.08 × 104
Hence, the molar volume is 7.08 × 104 times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
When the planet Jupiter is at a distance of 824.7 million kilometers from the Earth, its angular diameter is measured to be 35.72" of arc. Calculate the diameter of Jupiter.
The photograph of a house occupies an area of 1.75 cm2 on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m2. What is the linear magnification of the projector-screen arrangement?
It is a well known fact that during a total solar eclipse the disk of the moon almost completely covers the disk of the Sun. From this fact and from the information you can gather from examples 2.3 and 2.4, determine the approximate diameter of the moon.
Fill in the blanks
(a) The volume of a cube of side 1 cm is equal to.....m3
(b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ... (mm)2
(c) A vehicle moving with a speed of 18 km h–1covers....m in 1 s
(d) The relative density of lead is 11.3. Its density is ....g cm–3 or . ...kg m–3.
Explain this common observation clearly : If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train's motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you).
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A string of mass 2.50 kg is under a tension of 200 N. The length of the stretched string is 20.0 m. If the transverse jerk is struck at one end of the string, how long does the disturbance take to reach the other end?
A passenger arriving in a new town wishes to go from the station to a hotel located 10 km away on a straight road from the station. A dishonest cabman takes him along a circuitous path 23 km long and reaches the hotel in 28 min. What is
(a) the average speed of the taxi,
(b) the magnitude of average velocity? Are the two equal?
Two vessels have the same base area but different shapes. The first vessel takes twice the volume of water that the second vessel requires to fill upto a particular common height. Is the force exerted by the water on the base of the vessel the same in the two cases? If so, why do the vessels filled with water to that same height give different readings on a weighing scale?
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
A refrigerator is to maintain eatables kept inside at 9°C. If room temperature is 36° C, calculate the coefficient of performance.
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Explain why: (a) a body with large reflectivity is a poor emitter (b) a brass tumbler feels much colder than a wooden tray on a chilly day (c) an optical pyrometer (for measuring high temperatures) calibrated for an ideal black body radiation gives too low a value for the temperature of a red hot iron piece in the open, but gives a correct value for the temperature when the same piece is in the furnace (d) the earth without its atmosphere would be inhospitably cold (e) heating systems based on circulation of steam are more efficient in warming a building than those based on circulation of hot water
During blood transfusion the needle is inserted in a vein where the gauge pressure is 2000 Pa. At what height must the blood container be placed so that blood may just enter the vein? [Use the density of whole blood from Table 10.1].
The position-time (x-t) graphs for two children A and B returning from their school O to their homes P and Q respectively are shown in Fig. 3.19. Choose the correct entries in the brackets below;
(a) (A/B) lives closer to the school than (B/A)
(b) (A/B) starts from the school earlier than (B/A)
(c) (A/B) walks faster than (B/A)
(d) A and B reach home at the (same/different) time
(e) (A/B) overtakes (B/A) on the road (once/twice).
A steel rod 100 cm long is clamped at its middle. The fundamental frequency of longitudinal vibrations of the rod is given to be 2.53 kHz. What is the speed of sound in steel?