One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?
Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10-10 m
Volume of hydrogen atom = 4/3 π r3
= 4/3 x 22/7 x (0.5 x 10-10)3
= 0.524 x 1030 m3
1 mole of hydrogen contains 6.023 × 1023 hydrogen atoms.
∴ Volume of 1 mole of hydrogen atoms = 6.023 × 1023 × 0.524 × 10-30
= 3.16 × 10-7 m3
Molar volume of 1 mole of hydrogen atoms at STP,
Vm = 22.4 L = 22.4 × 10-3 m3
∴ Vm / Va = 22.4 x 10-3 / 3.16 × 10-7 = 7.08 × 104
Hence, the molar volume is 7.08 × 104 times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Rain is falling vertically with a speed of 30 m s–1. A woman rides a bicycle with a speed of 10 m s–1 in the north to south direction. What is the direction in which she should hold her umbrella?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
Figure 3.25 gives a speed-time graph of a particle in motion along a constant direction. Three equal intervals of time are shown. In which interval is the average acceleration greatest in magnitude? In which interval is the average speed greatest? Choosing the positive direction as the constant direction of motion, give the signs of v and a in the three intervals. What are the accelerations at the points A, B, C and D?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
An aircraft is flying at a height of 3400 m above the ground. If the angle subtended at a ground observation point by the aircraft positions 10.0 s apart is 30°, what is the speed of the aircraft?
You have learnt that a travelling wave in one dimension is represented by a function y = f (x, t) where x and t must appear in the combination x - v t or x + v t, i.e. y = f (x ± v t). Is the converse true? Examine if the following functions for y can possibly represent a travelling wave:
(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)
In Exercises 3.13 and 3.14, we have carefully distinguished between average speed and magnitude of average velocity. No such distinction is necessary when we consider instantaneous speed and magnitude of velocity. The instantaneous speed is always equal to the magnitude of instantaneous velocity. Why?
A stone dropped from the top of a tower of height 300 m high splashes into the water of a pond near the base of the tower. When is the splash heard at the top given that the speed of sound in air is 340 m s-1? (g= 9.8 m s-2)
A stone tied to the end of a string 80 cm long is whirled in a horizontal circle with a constant speed. If the stone makes 14 revolutions in 25 s, what is the magnitude and direction of acceleration of the stone?