Question 17

One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1Å). Why is this ratio so large?

Answer

Radius of hydrogen atom, r = 0.5 Å = 0.5 × 10^{-10} m

Volume of hydrogen atom = 4/3 π r^{3}

= 4/3 x 22/7 x (0.5 x 10^{-10})^{3}

= 0.524 x 10^{30} m^{3}

1 mole of hydrogen contains 6.023 × 10^{23} hydrogen atoms.

∴ Volume of 1 mole of hydrogen atoms = 6.023 × 10^{23} × 0.524 × 10^{-30 }

= 3.16 × 10^{-7} m^{3}

Molar volume of 1 mole of hydrogen atoms at STP,

V_{m} = 22.4 L = 22.4 × 10^{-3} m^{3}

∴ V_{m} / V_{a} = 22.4 x 10^{-3} / 3.16 × 10^{-7} = 7.08 × 10^{4}

Hence, the molar volume is 7.08 × 10^{4} times higher than the atomic volume. For this reason, the inter-atomic separation in hydrogen gas is much larger than the size of a hydrogen atom.

- Q:-
State the number of significant figures in the following:

(a) 0.007 m

^{2}(b) 2.64 x 10

^{24}kg(c) 0.2370 g cm

^{-3}(d) 6.320 J

(e) 6.032 N m

^{-2}(f) 0.0006032 m

^{2} - Q:-
Fill in the blanks by suitable conversion of units:

(a) 1 kg m

^{2}s^{–2}= ....g cm^{2 }s^{–2 }(b) 1 m =..... ly

(c) 3.0 m s

^{–2}=.... km h^{–2}(d) G = 6.67 × 10

^{–11}N m^{2}(kg)^{–2}=.... (cm)3s^{–2}g^{–1}. - Q:-
A physical quantity P is related to four observables a, b, c and d as follows :

The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?

- Q:-
Rain is falling vertically with a speed of 30 m s

^{–1}. A woman rides a bicycle with a speed of 10 m s^{–1}in the north to south direction. What is the direction in which she should hold her umbrella? - Q:- Give the magnitude and direction of the net force acting on

(a) a drop of rain falling down with a constant speed

(b) a cork of mass 10 g floating on water

(c) a kite skillfully held stationary in the sky

(d) a car moving with a constant velocity of 30 km/h on a rough road

(e) a high-speed electron in space far from all material objects, and free of electric and magnetic fields. - Q:-
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is

(a) the total mass of the box,

(b) the difference in the masses of the pieces to correct significant figures?

- Q:-
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.

- Q:-
What amount of heat must be supplied to 2.0 x 10

^{-2}kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N^{2}= 28; R = 8.3 J mol^{-1}K^{-1}.) - Q:- In which of the following examples of motion, can the body be considered approximately a point object:

(a) a railway carriage moving without jerks between two stations.

(b) a monkey sitting on top of a man cycling smoothly on a circular track.

(c) a spinning cricket ball that turns sharply on hitting the ground.

(d) a tumbling beaker that has slipped off the edge of a table. - Q:-
A transverse harmonic wave on a string is described by

y(x,t) = 3.0 sin [36t + 0.018x + π /4]

Where x and y are in cm and t in s. The positive direction of x is from left to right.

(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?

(b) What are its amplitude and frequency?

(c) What is the initial phase at the origin?

(d) What is the least distance between two successive crests in the wave?

- Q:-
Rain is falling vertically with a speed of 30 m s

^{–1}. A woman rides a bicycle with a speed of 10 m s^{–1}in the north to south direction. What is the direction in which she should hold her umbrella? - Q:-
Read each statement below carefully and state, with reasons, if it is true or false:

(a) The net acceleration of a particle in circular motion is always along the radius of the circle towards the centre

(b) The velocity vector of a particle at a point is always along the tangent to the path of the particle at that point

(c) The acceleration vector of a particle in uniform circular motion averaged over one cycle is a null vector

- Q:-
The blades of a windmill sweep out a circle of area A. (a) If the wind flows at a velocity v perpendicular to the circle, what is the mass of the air passing through it in time t?(b) What is the kinetic energy of the air? (c) Assume that the windmill converts 25% of the wind's energy into electrical energy, and that A = 30 m

^{2}, v = 36 km/h and the density of air is 1.2 kg m^{-3}. What is the electrical power produced? - Q:-
A travelling harmonic wave on a string is described by

y(x,t) = 7.5sin [0.0050x + 12t + π/4]

(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?

(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.

- Q:-
On a long horizontally moving belt (Fig. 3.26), a child runs to and fro with a speed 9 km h

^{-1}(with respect to the belt) between his father and mother located 50 m apart on the moving belt. The belt moves with a speed of 4 km h^{-1}. For an observer on a stationary platform outside, what is the(a) speed of the child running in the direction of motion of the belt ?.

(b) speed of the child running opposite to the direction of motion of the belt ?

(c) time taken by the child in (a) and (b) ? Which of the answers alter if motion is viewed by one of the parents?

(Figure 3.26)

- Q:-
**A block of mass 25 kg is raised by a 50 kg man in two different ways as shown in Fig. 5.19. What is the action on the floor by the man in the two cases? If the floor yields to a normal force of 700 N, which mode should the man adopt to lift the block without the floor yielding?** - Q:-
Toricelli's barometer used mercury. Pascal duplicated it using French wine of density 984 kg m

^{-3}. Determine the height of the wine column for normal atmospheric pressure. - Q:-
Though the statement quoted above may be disputed, most physicists do have a feeling that the great laws of physics are at once simple and beautiful. Some of the notable physicists, besides Dirac, who have articulated this feeling, are : Einstein, Bohr, Heisenberg, Chandrasekhar and Feynman. You are urged to make special efforts to get access to the general books and writings by these and other great masters of physics.

(See the Bibliography at the end of this book.) Their writings are truly inspiring !

- Q:-
Does it matter if one uses gauge instead of absolute pressures in applying Bernoulli's equation? Explain.

- Q:-
One end of a long string of linear mass density 8.0 x 10

^{-3 }kg m^{-1}is connected to an electrically driven tuning fork of frequency 256 Hz. The other end passes over a pulley and is tied to a pan containing a mass of 90 kg. The pulley end absorbs all the incoming energy so that reflected waves at this end have negligible amplitude. At t = 0, the left end (fork end) of the string x = 0 has zero transverse displacement (y = 0) and is moving along positive y-direction. The amplitude of the wave is 5.0 cm. Write down the transverse displacement y as function of x and t that describes the wave on the string.

- NCERT Chapter