Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Read each statement below carefully and state, with reasons, if it is true or false:
(a) The net acceleration of a particle in circular motion is always along the radius of the circle towards the centre
(b) The velocity vector of a particle at a point is always along the tangent to the path of the particle at that point
(c) The acceleration vector of a particle in uniform circular motion averaged over one cycle is a null vector
Two billiard balls each of mass 0.05 kg moving in opposite directions with speed 6 ms-1collide and rebound with the same speed. What is the impulse imparted to each ball due to the other?
A police van moving on a highway with a speed of 30 km h-1 fires a bullet at a thief's car speeding away in the same direction with a speed of 192 km h-1. If the muzzle speed of the bullet is 150 m s-1, with what speed does the bullet hit the thief's car ? (Note: Obtain that speed which is relevant for damaging the thief's car).
A cyclist starts from the centre O of a circular park of radius 1 km, reaches the edge P of the park, then cycles along the circumference, and returns to the centre along QO as shown in Fig. 4.21. If the round trip takes 10 min, what is the
(a) net displacement,
(b) average velocity, and
(c) average speed of the cyclist?
“Politics is the art of the possible”. Similarly, “Science is the art of the soluble”. Explain this beautiful aphorism on the nature and practice of science.
A pump on the ground floor of a building can pump up water to fill a tank of volume 30 m3 in 15 min. If the tank is 40 m above the ground, and the efficiency of the pump is 30%, how much electric power is consumed by the pump?
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
A great physicist of this century (P.A.M. Dirac) loved playing with numerical values of Fundamental constants of nature. This led him to an interesting observation. Dirac found that from the basic constants of atomic physics (c, e, mass of electron, mass of proton) and the gravitational constant G, he could arrive at a number with the dimension of time. Further, it was a very large number, its magnitude being close to the present estimate on the age of the universe (~15 billion years). From the table of fundamental constants in this book, try to see if you too can construct this number (or any other interesting number you can think of). If its coincidence with the age of the universe were significant, what would this imply for the constancy of fundamental constants?
Write in about 1000 words a fiction piece based on your speculation on the science and technology of the twenty-second century.
A refrigerator is to maintain eatables kept inside at 9°C. If room temperature is 36° C, calculate the coefficient of performance.