Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
The industrial revolution in England and Western Europe more than two centuries ago was triggered by some key scientific and technological advances. What were these advances ?
For the travelling harmonic wave
y (x, t) = 2.0 cos 2π (10t - 0.0080 x + 0.35)
Where x and y are in cm and t in s. Calculate the phase difference between oscillatory motion of two points separated by a distance of
(a) 4 m,
(b) 0.5 m,
(c) λ / 2 ,
(d) 3λ / 4
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
The motion of a body in simple harmonic motion is given by the displacement function,
x (t) = A cos (ωt + φ).
Given that at t = 0, the initial velocity of the body is ω cm/s and its initial position is 1 cm, calculate its initial phase angle and amplitude?
If in place of the cosine function, a sine function is used to represent the simple harmonic motion:
x = B sin (ωt + α),
calculate the body’s amplitude and initial phase considering the initial conditions given above. [Angular frequency of the particle is π/ s]
A cricketer can throw a ball to a maximum horizontal distance of 100 m. How much high above the ground can the cricketer throw the same ball?
The acceleration due to gravity on the surface of moon is 1.7 ms-2. What is the time period of a simple pendulum on the surface of moon if its time period on the surface of earth is 3.5 s? (g on the surface of earth is 9.8 ms-2)
A circular disc of mass 10 kg is suspended by a wire attached to its centre. The wire is twisted by rotating the disc and released. The period of torsional oscillations is found to be 1.5 s. The radius of the disc is 15 cm. Determine the torsional spring constant of the wire.
(Torsional spring constant α is defined by the relation J = -α ø, where J is the restoring couple and ø¸ the angle of twist).
Which of the following is the most precise device for measuring length:
(a) a vernier callipers with 20 divisions on the sliding scale
(b) a screw gauge of pitch 1 mm and 100 divisions on the circular scale
(c) an optical instrument that can measure length to within a wavelength of light ?
Figure 3.21 shows the x-t plot of one-dimensional motion of a particle. Is it correct to say from the graph that the particle moves in a straight line for t < 0 and on a parabolic path for t > 0? If not, suggest a suitable physical context for this graph.