Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Ten one-rupee coins are put on top of each other on a table. Each coin has a mass m. Give the magnitude and direction of
(a) the force on the 7th coin (counted from the bottom) due to all the coins on its top,
(b) the force on the 7th coin by the eighth coin,
(c) the reaction of the 6th coin on the 7th coin.
An aircraft executes a horizontal loop at a speed of 720 km/h with its wings banked at 15°. What is the radius of the loop?
A pebble of mass 0.05 kg is thrown vertically upwards. Give the direction and magnitude of the net force on the pebble,
(a) during its upward motion,
(b) during its downward motion,
(c) at the highest point where it is momentarily at rest.
Do your answers change if the pebble was thrown at an angle of 45° with the horizontal direction? Ignore air resistance.
A monkey of mass 40 kg climbs on a rope (Fig. 5.20) which can stand a maximum tension of 600 N. In which of the following cases will the rope break: the monkey
(a) climbs up with an acceleration of 6 m s-2
(b) climbs down with an acceleration of 4 m s-2
(c) climbs up with a uniform speed of 5 m s-1
(d) falls down the rope nearly freely under gravity?
(Ignore the mass of the rope).
A bob of mass 0.1 kg hung from the ceiling of a room by a string 2 m long is set into oscillation. The speed of the bob at its mean position is 1 ms-1. What is the trajectory of the bob if the string is cut when the bob is (a) at one of its extreme positions, (b) at its mean position.
For the travelling harmonic wave
y (x, t) = 2.0 cos 2π (10t - 0.0080 x + 0.35)
Where x and y are in cm and t in s. Calculate the phase difference between oscillatory motion of two points separated by a distance of
(a) 4 m,
(b) 0.5 m,
(c) λ / 2 ,
(d) 3λ / 4
A shell of mass 0.020 kg is fired by a gun of mass 100 kg. If the muzzle speed of the shell is 80 ms-1, what is the recoil speed of the gun?
A comet orbits the Sun in a highly elliptical orbit. Does the comet have a constant
(a) linear speed,
(b) angular speed,
(c) angular momentum,
(d) kinetic energy,
(e) potential energy,
(f) total energy throughout its orbit?
Neglect any mass loss of the comet when it comes very close to the Sun.
Fill in the blanks
(a) The volume of a cube of side 1 cm is equal to.....m3
(b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to ... (mm)2
(c) A vehicle moving with a speed of 18 km h–1covers....m in 1 s
(d) The relative density of lead is 11.3. Its density is ....g cm–3 or . ...kg m–3.