Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
Diameter of an oxygen molecule, d= 3Å
Radius, r = d /2 = 3/2 = 1.5 Å = 1.5 × 10-8 cm
Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3
Molecular volume of oxygen gas, V = 4/3 π r3 . N
Where, N is Avogadro's number = 6.023 × 1023 molecules/mole
∴ V = 4/3 x 3.14 x (1.5 × 10-8 )3 x 6.023 × 1023
= 8.51 cm3
Ratio of the molecular volume to the actual volume of oxygen = 8.51 / 22400 = 3.8 × 10-4
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
India has had a long and unbroken tradition of great scholarship — in mathematics, astronomy, linguistics, logic and ethics. Yet, in parallel with this, several superstitious and obscurantistic attitudes and practices flourished in our society and unfortunately continue even today — among many educated people too. How will you use your knowledge of science to develop strategies to counter these attitudes ?
A stone dropped from the top of a tower of height 300 m high splashes into the water of a pond near the base of the tower. When is the splash heard at the top given that the speed of sound in air is 340 m s-1? (g= 9.8 m s-2)
The shells of crabs found around a particular coastal location in Japan seem mostly to resemble the legendary face of a Samurai. Given below are two explanations of this observed fact. Which of these strikes you as a scientific explanation ?
(a) A tragic sea accident several centuries ago drowned a young Samurai. As a tribute to his bravery, nature through its inscrutable ways immortalised his face by imprinting it on the crab shells in that area.
(b) After the sea tragedy, fishermen in that area, in a gesture of honour to their dead hero, let free any crab shell caught by them which accidentally had a shape resembling the face of a Samurai. Consequently, the particular shape of the crab shell survived longer and therefore in course of time the shape was genetically propagated. This is an example of evolution by artificial selection.
[Note : This interesting illustration taken from Carl Sagan’s ‘The Cosmos’ highlights the fact that often strange and inexplicable facts which on the first sight appear ‘supernatural’ actually turn out to have simple scientific explanations. Try to think out other examples of this kind].
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
In Exercise 14.9, let us take the position of mass when the spring is unstreched as x = 0, and the direction from left to right as the positive direction of x-axis. Give x as a function of time t for the oscillating mass if at the moment we start the stopwatch (t = 0), the mass is
(a) at the mean position,
(b) at the maximum stretched position, and
(c) at the maximum compressed position.
In what way do these functions for SHM differ from each other, in frequency, in amplitude or the initial phase?
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Toricelli's barometer used mercury. Pascal duplicated it using French wine of density 984 kg m-3. Determine the height of the wine column for normal atmospheric pressure.
(a) A child stands at the centre of a turntable with his two arms outstretched. The turntable is set rotating with an angular speed of 40 rev/min. How much is the angular speed of the child if he folds his hands back and thereby reduces his moment of inertia to 2/5 times the initial value? Assume that the turntable rotates without friction.
(b) Show that the child’s new kinetic energy of rotation is more than the initial kinetic energy of rotation. How do you account for this increase in kinetic energy?