What is the effect of denaturation on the structure of proteins?
As a result of denaturation, globules get unfolded and helixes get uncoiled. Secondary and tertiary structures of protein are destroyed, but the primary structures remain unaltered. It can be said that during denaturation, secondary and tertiary-structured proteins get converted into primary-structured proteins. Also, as the secondary and tertiary structures of a protein are destroyed, the enzyme loses its activity.
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
What are nucleic acids? Mention their two important functions.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Given the standard electrode potentials,
K+/ K = - 2.93V,
Ag+/ Ag = 0.80V,
Hg2+ / Hg = 0.79V
Mg2+ / Mg = - 2.37 V,
Cr3+ / Cr = - 0.74V
Arrange these metals in their increasing order of reducing power.
What modification can you suggest in the Hardy-Schulze law?
State Henry's law and mention some important applications?
Give the equations of reactions for the preparation of phenol from cumene.
Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?
For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.
t (sec) | P(mm of Hg) |
0 | 35.0 |
360 | 54.0 |
720 | 63.0 |
Calculate the rate constant
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?
Explain on the basis of valence bond theory that [Ni(CN)4]2- ion with square planar structure is diamagnetic and the [Ni(CN)4]2- ion with tetrahedral geometry is paramagnetic.
Draw all the isomers (geometrical and optical) of:
(i) [CoCl2(en)2]+
(ii) [Co(NH3)Cl(en)2]2+
(iii) [Co(NH3)2Cl2(en)]+
Why has it been difficult to study the chemistry of radon?